{"title":"一种多孔pcu型Zn(II)配位聚合物的气体吸附和发光性能","authors":"Z. An, Jian Wang","doi":"10.1080/15533174.2015.1137061","DOIUrl":null,"url":null,"abstract":"A new Zn(II) compound, namely {Zn2(tdc)2(pi)}n (1 H2tdc = 2,5-thiophenedicarboxylic acid, pi = piperazine), has been synthesized via the solvothermal reactions of Zn(NO3)2·6H2O, H2tdc and pi. Single-crystal X-ray analysis reveals that compound 1 crystallizes in orthorhombic Pnma space group with cell parameters a = 20.734(6), b = 20.994(6), c = 18.539(6), and β = 90. The title compound features a three-dimensional (3D) pillar-layered framework. The gas adsorption and luminescent properties of 1 were investigated in the solid state at room temperature.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":"29 1","pages":"1810 - 1814"},"PeriodicalIF":0.0000,"publicationDate":"2016-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":"{\"title\":\"Gas Adsorption and Luminescent Properties of a Porous pcu-Type Zn(II) Coordination Polymer\",\"authors\":\"Z. An, Jian Wang\",\"doi\":\"10.1080/15533174.2015.1137061\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A new Zn(II) compound, namely {Zn2(tdc)2(pi)}n (1 H2tdc = 2,5-thiophenedicarboxylic acid, pi = piperazine), has been synthesized via the solvothermal reactions of Zn(NO3)2·6H2O, H2tdc and pi. Single-crystal X-ray analysis reveals that compound 1 crystallizes in orthorhombic Pnma space group with cell parameters a = 20.734(6), b = 20.994(6), c = 18.539(6), and β = 90. The title compound features a three-dimensional (3D) pillar-layered framework. The gas adsorption and luminescent properties of 1 were investigated in the solid state at room temperature.\",\"PeriodicalId\":22118,\"journal\":{\"name\":\"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry\",\"volume\":\"29 1\",\"pages\":\"1810 - 1814\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2016-05-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1080/15533174.2015.1137061\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/15533174.2015.1137061","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 2
摘要
通过Zn(NO3)2·6H2O、H2tdc和pi的溶剂热反应，合成了新的Zn(II)化合物{Zn2(tdc)2(pi)}n (1 H2tdc = 2,5-噻吩二羧酸，pi =哌嗪)。单晶x射线分析表明，化合物1在正交Pnma空间群中结晶，晶胞参数a = 20.734(6)， b = 20.994(6)， c = 18.539(6)， β = 90。标题化合物具有三维(3D)柱状分层框架。研究了1在室温下的固态气体吸附和发光性能。
Gas Adsorption and Luminescent Properties of a Porous pcu-Type Zn(II) Coordination Polymer
A new Zn(II) compound, namely {Zn2(tdc)2(pi)}n (1 H2tdc = 2,5-thiophenedicarboxylic acid, pi = piperazine), has been synthesized via the solvothermal reactions of Zn(NO3)2·6H2O, H2tdc and pi. Single-crystal X-ray analysis reveals that compound 1 crystallizes in orthorhombic Pnma space group with cell parameters a = 20.734(6), b = 20.994(6), c = 18.539(6), and β = 90. The title compound features a three-dimensional (3D) pillar-layered framework. The gas adsorption and luminescent properties of 1 were investigated in the solid state at room temperature.
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