NaOH和KOH存在下食品砖Pet-Al渣反应制氢

A. Souilhi, R. Abidi
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引用次数: 1

摘要

铝被堆放在食物砖的两层聚乙烯之间,是生产氢的一种能源,在我们这个时代是非常需要的。在T=40、60和80℃条件下,NaOH和KOH水溶液浓度为1 ~ 10 M时,反应的活化能Ea (NaOH)=36416 j.l l-1低于T=60℃、浓度为4 M条件下的Ea (KOH),反应受温度和浓度的影响较大。氢氧化钠通常促进更经济有效的反应。对残碱溶液进行酸处理后,得到了带有盐(NaCl或KCl)的氢氧化铝,并通过SEM和IR验证了氢氧化铝的性质。
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Production of Hydrogen by Reaction of Pet-Al Residues of Food Bricks in the Presence of NaOH and KOH
Aluminum being stacked between two layers of polyethylene in food bricks, is a source of hydrogen production highly demanded as energy in our days. With aqueous solutions of NaOH and KOH at concentrations ranging from 1 M to 10 M for T=40, 60 and 80°C, we conclude that the activation energy Ea (NaOH)=36416 J.mol-1 is lower than that of Ea (KOH) at T=60°C and a concentration of 4 M, the reaction is strongly influenced by temperature and concentration. Sodium hydroxide generally promotes more cost-effective reactions. Obtaining an aluminum hydroxide accompanied by salt (NaCl or KCl) after acid treatment of the residual alkaline solution was verified by SEM and IR, thus preserving the nature.
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