{"title":"一种新型吡啶羧酸配体Dy(III)化合物的合成、晶体结构和热分析","authors":"Hui-min Liu","doi":"10.1080/15533174.2015.1137066","DOIUrl":null,"url":null,"abstract":"A new compound, namely [Dy4(L)6(H2O)4]n (1 H2L = 5-(pyridin-4-ylmethoxy)-isophthalic acid), has been hydrothermally synthesized and further characterized by the single-crystal X-ray diffraction, elemental analysis, infrared spectroscopy. Single-crystal X-ray diffraction analysis reveals that compound 1 crystallizes in monoclinic P21/n space group with a = 24.0566(5), b = 14.3950(3), c = 26.0162(6), and β = 92.146(2)°. In the compound, there are two different 1D chains constructed by L2− ligands and Dy(III) ions, which are further bridged by the L2− ligands into a complicated 3D framework.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":"138 1","pages":"1792 - 1795"},"PeriodicalIF":0.0000,"publicationDate":"2016-05-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis, Crystal Structure, and Thermal Analysis of a New Dy(III) Compound Based on Pyridinecarboxylate Ligand\",\"authors\":\"Hui-min Liu\",\"doi\":\"10.1080/15533174.2015.1137066\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A new compound, namely [Dy4(L)6(H2O)4]n (1 H2L = 5-(pyridin-4-ylmethoxy)-isophthalic acid), has been hydrothermally synthesized and further characterized by the single-crystal X-ray diffraction, elemental analysis, infrared spectroscopy. Single-crystal X-ray diffraction analysis reveals that compound 1 crystallizes in monoclinic P21/n space group with a = 24.0566(5), b = 14.3950(3), c = 26.0162(6), and β = 92.146(2)°. In the compound, there are two different 1D chains constructed by L2− ligands and Dy(III) ions, which are further bridged by the L2− ligands into a complicated 3D framework.\",\"PeriodicalId\":22118,\"journal\":{\"name\":\"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry\",\"volume\":\"138 1\",\"pages\":\"1792 - 1795\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2016-05-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1080/15533174.2015.1137066\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/15533174.2015.1137066","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
摘要
用水热法合成了一个新化合物[Dy4(L)6(H2O)4]n (1 H2L = 5-(吡啶-4-基甲氧基)-间苯二甲酸)，并用单晶x射线衍射、元素分析、红外光谱对其进行了表征。单晶x射线衍射分析表明，化合物1在单斜P21/n空间群中结晶，a = 24.0566(5)， b = 14.3950(3)， c = 26.0162(6)， β = 92.146(2)°。在该化合物中，有由L2 -配体和Dy(III)离子构成的两个不同的1D链，它们被L2 -配体进一步桥接成一个复杂的3D框架。
Synthesis, Crystal Structure, and Thermal Analysis of a New Dy(III) Compound Based on Pyridinecarboxylate Ligand
A new compound, namely [Dy4(L)6(H2O)4]n (1 H2L = 5-(pyridin-4-ylmethoxy)-isophthalic acid), has been hydrothermally synthesized and further characterized by the single-crystal X-ray diffraction, elemental analysis, infrared spectroscopy. Single-crystal X-ray diffraction analysis reveals that compound 1 crystallizes in monoclinic P21/n space group with a = 24.0566(5), b = 14.3950(3), c = 26.0162(6), and β = 92.146(2)°. In the compound, there are two different 1D chains constructed by L2− ligands and Dy(III) ions, which are further bridged by the L2− ligands into a complicated 3D framework.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
