新型合成双酮酸酯配位生物聚合物衍生物在生物医学、制药和食品工业中的应用前景

R. Hassan
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引用次数: 6

摘要

用高锰酸钾在碱性溶液中氧化果胶溶胶,在pH为bbb12的条件下定量合成了双酮酸酯(PDK)。收率为97.3%。合成的果胶二酮的化学结构经元素分析和光谱分析证实。当PDK加入到多价金属离子电解质中时,观察到溶胶-凝胶转变和/或沉淀。提出并讨论了合成过程的反应机理。
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Novel Synthesis of Diketopectate Coordination Biopolymer Derivatives as Alternative Promising In Biomedicine, Pharmaceutics and Food Industrial Applications
Diketopectates (PDK) was quantitatively synthesized by the oxidation of pectin sol with potassium permanganate in alkaline solutions at pH`s > 12. The yield was 97.3 %. The chemical structure of such synthesized pectate-diketones was elucidated by elemental analysis and spectroscopic data. Sol-gel transformation and/or precipitation were observed when PDK was added to polyvalent metal ion electrolytes. The reaction mechanism of synthesis process was suggested and discussed.
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