在土壤中处理聚羟基丁酸酯-共羟戊酸酯(PHBV)混合物作为低密度聚乙烯替代品的好处

Elaine Cristina Bucioli, A. Faria, ra Mara Martins-Franchetti, Lusiane Malafatti Picca, D. Attili-Angelis
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摘要

合成塑料的使用由于其生物可降解性低和处理不当而对环境产生影响。减少这一问题的替代方法之一是使用可生物降解聚合物和/或生产具有理想工业和环保特性的混合物。采用扫描电镜(SEM)、傅里叶变换红外(FTIR)和质量损失等方法评价了PHBV(聚羟基丁酸酯-共羟戊酸酯)、LDPE(低密度聚乙烯)和LDPE / PHBV(70/30)共混物在土壤柱中的生物降解效果。通过扫描电镜可以观察到PHBV和共混物表面的微观形态变化,这些变化与质量损失的变化相一致。PHBV样品在生物降解过程中减少了43.9%,混合物减少了15.7%。FTIR分析显示,聚合物材料的结晶度发生了变化,表明这些薄膜发生了生物降解。通过测定土壤样品的pH、有机质(%)、水分(%)和微生物群落的CFU来表征土壤样品。混合料易受土壤微生物活动的影响,其微观形态发生显著变化。使用的70/30比例(LDPE/ PHBV)表现出对土壤微生物的敏感性,有利于土壤微生物群落的增加。聚合物共混物的使用也有利于减少存在于环境中的聚合物的数量,因为其中一些是可生物降解的。
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Benefits of Disposing Polyhydroxybutyrate-Co-Hydroxyvalerate (PHBV) Blends in Soil, as Alternative for Low Density Polyethylene
The use of synthetic plastics generates environmental impacts due to their low biodegradability and inadequate disposal. One of the alternatives to minimize this problem is the use of biodegradable polymers and/or the production of blends with desired industrial and eco-friendly characteristics. The biodegradation of PHBV (Poly (Hydroxybutyrate-co-Hydroxyvalerate)), LDPE (Low Density Polyethylene) and LDPE / PHBV (70/30) blends in soil column was evaluated using Scanning Electron Microscopy (SEM), Fourier Transform Infrared (FTIR), and mass loss. Through SEM it was possible to observe micro morphological changes on the surface of the PHBV and the blends, in accordance with the mass loss variation. PHBV samples showed a reduction of 43.9 % and the blend had a reduction of 15.7 %, during their biodegradation process. FTIR analysis revealed that the crystallinity of the polymeric materials changed, suggesting the biodegradation of these films. Soil samples were characterized by determination of pH, organic matter (%), moisture (%), and CFU of the microbial community. The blend was susceptible to soil microbial activity, with significant changes in its micro morphology. The used 70/30 ratio (LDPE/ PHBV) showed susceptibility to soil microorganisms, favoring the increase of its microbial community. The use of polymeric blends also favors the reduction of the amount of polymers present in the environment because some of them are biodegradable.
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