{"title":"a位取代对Mn3O4尖晶石介电和阻抗行为的影响","authors":"Nayana Acharya, Raghavendra Sagar","doi":"10.1080/07315171.2019.1647719","DOIUrl":null,"url":null,"abstract":"Abstract In this paper, we report the influence of A-site substitution on dielectric and electrical behavior of Mn3O4 based modified spinels at room temperature. All the three spinels substituted with Mn, Zn and Co at A-site showed slight decrease in relative permittivity (ε′) and dissipation factor (tanδ) in the studied frequency range of 40 Hz to 8 MHz. However, the influence of A-site substitution was noticeable because of it dominant influence on relative permittivity and dissipation factor over pure Mn3O4 spinel. The relative permittivity increased from ∼ 16 to 95 after substitution of Zn in A-site whereas the substitution of Co increased the magnitude upto 40. Similar trend was observed with tan δ measurement after A-site substitution. The frequency dependent impedance measurement revealed the better conducting behavior of pure and modified spinels because of its low impedance range and better frequency dependent ac-conductivity.","PeriodicalId":50451,"journal":{"name":"Ferroelectrics Letters Section","volume":null,"pages":null},"PeriodicalIF":1.3000,"publicationDate":"2019-06-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"4","resultStr":"{\"title\":\"Influence of A-site substitution on dielectric and impedance behavior of Mn3O4 spinels\",\"authors\":\"Nayana Acharya, Raghavendra Sagar\",\"doi\":\"10.1080/07315171.2019.1647719\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract In this paper, we report the influence of A-site substitution on dielectric and electrical behavior of Mn3O4 based modified spinels at room temperature. All the three spinels substituted with Mn, Zn and Co at A-site showed slight decrease in relative permittivity (ε′) and dissipation factor (tanδ) in the studied frequency range of 40 Hz to 8 MHz. However, the influence of A-site substitution was noticeable because of it dominant influence on relative permittivity and dissipation factor over pure Mn3O4 spinel. The relative permittivity increased from ∼ 16 to 95 after substitution of Zn in A-site whereas the substitution of Co increased the magnitude upto 40. Similar trend was observed with tan δ measurement after A-site substitution. The frequency dependent impedance measurement revealed the better conducting behavior of pure and modified spinels because of its low impedance range and better frequency dependent ac-conductivity.\",\"PeriodicalId\":50451,\"journal\":{\"name\":\"Ferroelectrics Letters Section\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.3000,\"publicationDate\":\"2019-06-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"4\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Ferroelectrics Letters Section\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://doi.org/10.1080/07315171.2019.1647719\",\"RegionNum\":4,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"PHYSICS, CONDENSED MATTER\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Ferroelectrics Letters Section","FirstCategoryId":"101","ListUrlMain":"https://doi.org/10.1080/07315171.2019.1647719","RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"PHYSICS, CONDENSED MATTER","Score":null,"Total":0}
Influence of A-site substitution on dielectric and impedance behavior of Mn3O4 spinels
Abstract In this paper, we report the influence of A-site substitution on dielectric and electrical behavior of Mn3O4 based modified spinels at room temperature. All the three spinels substituted with Mn, Zn and Co at A-site showed slight decrease in relative permittivity (ε′) and dissipation factor (tanδ) in the studied frequency range of 40 Hz to 8 MHz. However, the influence of A-site substitution was noticeable because of it dominant influence on relative permittivity and dissipation factor over pure Mn3O4 spinel. The relative permittivity increased from ∼ 16 to 95 after substitution of Zn in A-site whereas the substitution of Co increased the magnitude upto 40. Similar trend was observed with tan δ measurement after A-site substitution. The frequency dependent impedance measurement revealed the better conducting behavior of pure and modified spinels because of its low impedance range and better frequency dependent ac-conductivity.
期刊介绍：
Ferroelectrics Letters is a separately published section of the international journal Ferroelectrics. Both sections publish theoretical, experimental and applied papers on ferroelectrics and related materials, including ferroelastics, ferroelectric ferromagnetics, electrooptics, piezoelectrics, pyroelectrics, nonlinear dielectrics, polymers and liquid crystals.
Ferroelectrics Letters permits the rapid publication of important, quality, short original papers on the theory, synthesis, properties and applications of ferroelectrics and related materials.
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