含钙藜蛋白的活性位点模型

Journal of The Chemical Society, Chemical Communications Pub Date : 1996-02-27 DOI:10.1039/C39950002077

S. Itoh, Xin Huang, H. Kawakami, M. Komatsu, Y. Ohshiro, S. Fukuzumi

{"title":"含钙藜蛋白的活性位点模型","authors":"S. Itoh, Xin Huang, H. Kawakami, M. Komatsu, Y. Ohshiro, S. Fukuzumi","doi":"10.1039/C39950002077","DOIUrl":null,"url":null,"abstract":"The Ca2+ complexes of PQQ-2, 9-dimethyl ester and its iminoquinone derivative have been synthesised and the reactivity towards alcohols examined; the oxidising ability of the quinone is significantly enhanced by binding Ca2+ and NH3, both of which are essential for quinoprotein methanol dehydrogenase activation.","PeriodicalId":17282,"journal":{"name":"Journal of The Chemical Society, Chemical Communications","volume":"76 1","pages":"2077-2078"},"PeriodicalIF":0.0000,"publicationDate":"1996-02-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"7","resultStr":"{\"title\":\"An active site model for calcium(II)-containing quinoproteins\",\"authors\":\"S. Itoh, Xin Huang, H. Kawakami, M. Komatsu, Y. Ohshiro, S. Fukuzumi\",\"doi\":\"10.1039/C39950002077\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The Ca2+ complexes of PQQ-2, 9-dimethyl ester and its iminoquinone derivative have been synthesised and the reactivity towards alcohols examined; the oxidising ability of the quinone is significantly enhanced by binding Ca2+ and NH3, both of which are essential for quinoprotein methanol dehydrogenase activation.\",\"PeriodicalId\":17282,\"journal\":{\"name\":\"Journal of The Chemical Society, Chemical Communications\",\"volume\":\"76 1\",\"pages\":\"2077-2078\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1996-02-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"7\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society, Chemical Communications\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/C39950002077\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society, Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C39950002077","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}

引用次数: 7

摘要

合成了pqc - 2,9 -二甲酯及其亚氨基醌衍生物的Ca2+配合物，并测定了其对醇的反应性;醌的氧化能力通过与醌蛋白甲醇脱氢酶激活所必需的Ca2+和NH3结合而显著增强。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文

微信好友朋友圈 QQ好友复制链接

本刊更多论文

An active site model for calcium(II)-containing quinoproteins

The Ca2+ complexes of PQQ-2, 9-dimethyl ester and its iminoquinone derivative have been synthesised and the reactivity towards alcohols examined; the oxidising ability of the quinone is significantly enhanced by binding Ca2+ and NH3, both of which are essential for quinoprotein methanol dehydrogenase activation.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊