植物修复对尼日利亚乌卡里机械村农业土壤多环芳烃水平的影响

Itodo Au, R. Shaato, Wuana Ra, E. Yerima
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引用次数: 2

摘要

采用气相色谱-质谱联用技术,对乌卡里梅克克村周边农业土壤中多环芳烃的组成进行了标准测定。利用多环芳烃来源诊断率分析,推断了土壤中多环芳烃的可能来源。风险评估依据美国环境保护署《定量风险评估临时指南》提出的多环芳烃终生致癌增量风险。间作玉米(SMV-MS)、单独间作玉米(SMV-M)、间作玉米(SMV-MSF)和单独间作玉米(SMV-MF)的植物修复效果结果表明:以环流行度为基础的机械村周边农业土壤多环芳烃组成依次为Σ5 >Σ6 >Σ4 >Σ3 >Σ2环。二苯并[a,h]蒽4.52 μg/kg(39.09%)丰度最高,但低于加拿大农业和商业布局土壤质量指标100 μg/kg和700 μg/kg,苊0.111 μg/kg(0.90%)丰度最低。诊断比分析表明,土壤中多环芳烃的来源基本为热原源,而玉米间种金刺草对土壤进行植物修复后,土壤中多环芳烃含量显著降低。
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Effect of Phytoremediation on PAHs Levels of Agricultural Soil around Mechanic Village Wukari, Nigeria
This study evaluates the PAHs composition in agricultural soils around Mechanic village, Wukari using standard procedures by means of GC-MS. The possible source of the PAHs in the soil was deduced, using the diagnostic ratio analysis for PAH origin. Risk assessment was based on the incremental life cancer risk of PAHs proposed by Provisional Guidance for Quantitative Risk Assessment of the United States Environmental Protection Agency. Effect of phyto-remediation using Zea mays inter-planted with Striga hermonthica (SMV-MS), Zea mays alone (SMV-M), Zea mays inter-planted with Striga hermonthica alongside the application of fertilizer (SMV-MSF) and Zea mays alone alongside fertilizer application (SMV-MF). The result reveals that the PAHs composition based on ring prevalence in agricultural soils around Mechanic village Wukari was in the order Σ5 >Σ6 >Σ4 >Σ3 >Σ2 ring. Dibenz [a,h] anthracene 4.52 μg/kg (39.09%) has the highest percentage abundance but was less than the 100 μg/kg and 700 μg/kg Canadian soil quality guideline for agricultural and commercial layout while acenaphthene 0.111 μg/kg (0.90%) was the least abundant. The source of the PAHs in the soil was basically pyrogenic based on the diagnostic ratio analysis while phytoremediation of the soil using Zea mays inter-planted with Striga hermonthica significantly reduce the PAHs content of the soil.
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