在隐式化合物和大环冠醚化合物存在下，甲醇和正丁醇的碱金属盐引发甲基丙烯酸甲酯的均相聚合

British Polymer Journal Pub Date : 1986-05-01 DOI:10.1002/PI.4980180306

M. Viguier, A. Collet, F. Schué, B. Mula

{"title":"在隐式化合物和大环冠醚化合物存在下，甲醇和正丁醇的碱金属盐引发甲基丙烯酸甲酯的均相聚合","authors":"M. Viguier, A. Collet, F. Schué, B. Mula","doi":"10.1002/PI.4980180306","DOIUrl":null,"url":null,"abstract":"The polymerisation of methylmethacrylate initiated by alkali alkoxides is greatly promoted in the presence of macrocyclic compounds, cryptands and crown ethers. The solubility in toluene and the reactivity of alkoxides is enhanced by these complexing agents. Polymerisations have been carried out in a non-polar solvent in the homogeneous phase.","PeriodicalId":9298,"journal":{"name":"British Polymer Journal","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1986-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Homogeneous polymerisation of methylmethacrylate initiated by alkali metal salts of methanol and t-butyl alcohol in the presence of cryptands and macrocyclic crown ether compounds\",\"authors\":\"M. Viguier, A. Collet, F. Schué, B. Mula\",\"doi\":\"10.1002/PI.4980180306\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The polymerisation of methylmethacrylate initiated by alkali alkoxides is greatly promoted in the presence of macrocyclic compounds, cryptands and crown ethers. The solubility in toluene and the reactivity of alkoxides is enhanced by these complexing agents. Polymerisations have been carried out in a non-polar solvent in the homogeneous phase.\",\"PeriodicalId\":9298,\"journal\":{\"name\":\"British Polymer Journal\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1986-05-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"British Polymer Journal\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1002/PI.4980180306\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"British Polymer Journal","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1002/PI.4980180306","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}

引用次数: 1

摘要

在大环化合物、隐式化合物和冠醚的存在下，碱烷基氧化物引发的甲基丙烯酸甲酯的聚合得到了极大的促进。这些络合剂提高了在甲苯中的溶解度和醇氧化物的反应性。聚合已在均相的非极性溶剂中进行。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文

微信好友朋友圈 QQ好友复制链接

本刊更多论文

Homogeneous polymerisation of methylmethacrylate initiated by alkali metal salts of methanol and t-butyl alcohol in the presence of cryptands and macrocyclic crown ether compounds

The polymerisation of methylmethacrylate initiated by alkali alkoxides is greatly promoted in the presence of macrocyclic compounds, cryptands and crown ethers. The solubility in toluene and the reactivity of alkoxides is enhanced by these complexing agents. Polymerisations have been carried out in a non-polar solvent in the homogeneous phase.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

British Polymer Journal

自引率

0.00%

发文量