Cr/ nnn催化乙烯低聚反应的链生长机制研究

Jiale Peng, Mengyu Zhu, Long Chen, Z. Liu
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引用次数: 1

摘要

本文采用密度分析方法系统地研究了一种特殊的、有争议的Cr/NNN乙烯低聚体系,该体系以Schulz-Flory分布传递低聚物,并被认为遵循金属循环机制。
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Unravelling the chain growth mechanism in Cr/NNN-catalysed ethylene oligomerization
A special and controversial Cr/NNN ethylene oligomerization system delivering oligomers in a Schulz-Flory distribution, which was suggested to follow a metallacycle mechanism, has been systematically investigated by means of density...
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