利用高强度红外辐射快速高效地消解贱金属矿石样品,并用氮基微波等离子体光谱法测定

Yong Wang, Laura A. Baker, Erick Helmeczi, Ian D. Brindle
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引用次数: 11

摘要

红外样品消解技术是近年来迅速发展起来的一项技术,本文利用6通道红外消解器,对红外消解技术在多种贱金属矿石中的应用及消解性能进行了评价。所有被研究的贱金属矿石,包括Co、Cr、Cu、Fe、Mn、Mo、Ni、Pb、Sb、Ti、W和Zn的氧化物、硫化物和硅酸盐,消解时间均在10分钟或更短。所有样本的性能标准都很好,在所有情况下z值都小于2。在高强度红外辐射下,对选定的矿石样品开发了各种酸消解方法,并几乎完全回收了所有感兴趣的元素。铬铁矿是出了名的难熔铬矿,在10分钟内被消化,铬的回收率达到100%。这些消化在不使用高氯酸的情况下完成,对于大多数样品类型,不使用氢氟酸,大大提高了分析人员工作场所的安全性。6通道单元的分析物回收率的通道间变化通常低于2%,表明该平台开发的消化方法具有可重复性,可满足各种样品制备要求。这些消化的高速度和分析物回收率使这种方法对要求从勘探样品中获得快速可靠结果的勘探者和开发商特别有吸引力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Rapid high-performance sample digestion of base metal ores using high-intensity infrared radiation with determination by nitrogen-based microwave plasma optical spectrometry

Infrared sample digestion technology has been rapidly developed in recent years and its application and digestion performance on a variety of ores of base metals was assessed in this study, using a 6-channel infrared digester. Digestion times of 10 min or less were achieved for all base metal ores investigated, including oxides, sulfides, and silicates of Co, Cr, Cu, Fe, Mn, Mo, Ni, Pb, Sb, Ti, W, and Zn. Performance criteria for all samples were excellent, reflected in z values of less than 2 in all cases. Various acid digestion methods were developed for the selected ore samples under high intensity infrared radiation and delivered virtually complete recoveries of all of the elements of interest. Chromite, the notoriously refractory chromium ore was digested within 10 min and gave 100% recovery of chromium. These digestions were accomplished without resorting to perchloric acid and, for most sample types, without hydrofluoric acid, significantly improving the workplace safety for analysts. Between-channel variation of the analyte recoveries from the 6-channel unit were generally below 2%, suggesting that the digestion methods developed with this platform provide reproducible results to meet various sample preparation demands. The high speed and analyte recovery of these digestions makes this methodology especially attractive for prospectors and developers who demand rapid and reliable results from exploration samples.

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