双(n -乙基- n -苯基二硫代氨基-κ 2s,S ')-(2-乙基-2-恶唑啉-κ 1n)锌(II)的晶体结构

Robert A. Gossage, H. Jenkins
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引用次数: 3

摘要

用过量的2-乙基-2-恶唑啉处理[Zn{S2CN(Et)(Ph)}2]2,合成了标题材料。晶系为三斜晶系(空间群P1, Z = 2),晶胞尺寸为a = 10.2310(4) a, b = 11.4701(5) a, c = 12.1981(5) a, α = 85.952(1)°,β = 75.174(1)°,γ = 72.442(1)°,V = 1319.30(9)A3。最终R值为0.0248(4641次观测反射:I > 2σ(I))。锌原子与两个螯合二硫代氨基和一个n键恶唑啉配位。
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Crystal Structure of Bis(N-ethyl-N-phenyldithiocarbamato-κ2S,S′)-(2-ethyl-2-oxazoline-κ1N)zinc(II)
The title material was synthesised by the treatment of [Zn{S2CN(Et)(Ph)}2]2 with excess 2-ethyl-2-oxazoline. The crystal system is triclinic (space group P1 and Z = 2). The unit-cell dimensions are a = 10.2310(4)A, b = 11.4701(5)A, c = 12.1981(5)A with α = 85.952(1)°, β = 75.174(1)°, γ = 72.442(1)° and V = 1319.30(9)A3. The final R value is 0.0248 (4641 observed reflections: I > 2σ(I)). The Zn atom coordinates with two chelating dithiocarbamato groups and one N-bound oxazoline.
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