{"title":"红外强度测量- 1。实验条件和标准波段","authors":"J.T. Shimozawa , M.K. Wilson","doi":"10.1016/0371-1951(66)80159-5","DOIUrl":null,"url":null,"abstract":"<div><p>The experimental conditions for the measurement of absolute infrared intensities of vibrational transitions have been examined using the out-of-plane CH vibration of 1,2,4,5-tetrachlorobenzone. This symmetrical band has been investigated in solution in carbon disulfide. The band was analyzed by the band shape moment analysis. The error in the experimentally determined intensity is estimated to be ±5 percent. It is suggested that this band would be useful as an intensity standard in condensed systems.</p></div>","PeriodicalId":101180,"journal":{"name":"Spectrochimica Acta","volume":"22 9","pages":"Pages 1591-1597"},"PeriodicalIF":0.0000,"publicationDate":"1966-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0371-1951(66)80159-5","citationCount":"10","resultStr":"{\"title\":\"Infrared intensity measurements—I. Experimental conditions and a standard band\",\"authors\":\"J.T. Shimozawa , M.K. Wilson\",\"doi\":\"10.1016/0371-1951(66)80159-5\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The experimental conditions for the measurement of absolute infrared intensities of vibrational transitions have been examined using the out-of-plane CH vibration of 1,2,4,5-tetrachlorobenzone. This symmetrical band has been investigated in solution in carbon disulfide. The band was analyzed by the band shape moment analysis. The error in the experimentally determined intensity is estimated to be ±5 percent. It is suggested that this band would be useful as an intensity standard in condensed systems.</p></div>\",\"PeriodicalId\":101180,\"journal\":{\"name\":\"Spectrochimica Acta\",\"volume\":\"22 9\",\"pages\":\"Pages 1591-1597\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1966-09-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0371-1951(66)80159-5\",\"citationCount\":\"10\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Spectrochimica Acta\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0371195166801595\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Spectrochimica Acta","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0371195166801595","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Infrared intensity measurements—I. Experimental conditions and a standard band
The experimental conditions for the measurement of absolute infrared intensities of vibrational transitions have been examined using the out-of-plane CH vibration of 1,2,4,5-tetrachlorobenzone. This symmetrical band has been investigated in solution in carbon disulfide. The band was analyzed by the band shape moment analysis. The error in the experimentally determined intensity is estimated to be ±5 percent. It is suggested that this band would be useful as an intensity standard in condensed systems.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
