{"title":"胍盐Bis (pyridine-2 6-dicarboxylato-N, O, O)锰(II)","authors":"D. Boghaei, M. Najafpour","doi":"10.2116/ANALSCIX.24.X23","DOIUrl":null,"url":null,"abstract":"Numerous complexes of pyridinecarboxylic acids with transition metals have been investigated because of their interesting structural, redox and water oxidation properties. 1,2 Pyridine-2,6-dicarboxylic (dipicolinic) acid has been demonstrated in spores of aerobic and anaerobic bacteria. It is released during the germination of spores of aerobes. Pyridine-2,6-dicarboxylic forms a metal complex with divalent metal ions, especially with manganese and calcium. 3 Also the guanidinium cation has an important role in enzymes; for example, X-ray structural evidence places the guanidinium cation of the conserved arginine 357 residue of CP43 within a few Å to the Mn 4 Ca cluster of the water-oxidizing complex (WOC) in photosystem II. 4 The title complex was synthesized and structurally characterized by single-crystal X-ray diffraction. This complex was solved in the triclinic system, space group P 1 , with the following unit-cell parameters: a = 8.5657(4)Å, b = 10.9848(5)Å, c = 13.1681(6)Å, α = 112.617(1)˚, β = 99.646(1)˚, δ = 90.849(1)˚, Z = 2, V = 1123.28(9)Å 3 . The final R value was R 1 = 0.0344 for 15675 measured reflections.","PeriodicalId":7796,"journal":{"name":"Analytical Sciences: X-ray Structure Analysis Online","volume":"108 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2008-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Guanidinium Bis(pyridine-2,6-dicarboxylato-N,O,O)manganese(II)\",\"authors\":\"D. Boghaei, M. Najafpour\",\"doi\":\"10.2116/ANALSCIX.24.X23\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Numerous complexes of pyridinecarboxylic acids with transition metals have been investigated because of their interesting structural, redox and water oxidation properties. 1,2 Pyridine-2,6-dicarboxylic (dipicolinic) acid has been demonstrated in spores of aerobic and anaerobic bacteria. It is released during the germination of spores of aerobes. Pyridine-2,6-dicarboxylic forms a metal complex with divalent metal ions, especially with manganese and calcium. 3 Also the guanidinium cation has an important role in enzymes; for example, X-ray structural evidence places the guanidinium cation of the conserved arginine 357 residue of CP43 within a few Å to the Mn 4 Ca cluster of the water-oxidizing complex (WOC) in photosystem II. 4 The title complex was synthesized and structurally characterized by single-crystal X-ray diffraction. This complex was solved in the triclinic system, space group P 1 , with the following unit-cell parameters: a = 8.5657(4)Å, b = 10.9848(5)Å, c = 13.1681(6)Å, α = 112.617(1)˚, β = 99.646(1)˚, δ = 90.849(1)˚, Z = 2, V = 1123.28(9)Å 3 . The final R value was R 1 = 0.0344 for 15675 measured reflections.\",\"PeriodicalId\":7796,\"journal\":{\"name\":\"Analytical Sciences: X-ray Structure Analysis Online\",\"volume\":\"108 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2008-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Analytical Sciences: X-ray Structure Analysis Online\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.2116/ANALSCIX.24.X23\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Analytical Sciences: X-ray Structure Analysis Online","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2116/ANALSCIX.24.X23","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
摘要
许多吡啶羧酸与过渡金属的配合物由于其有趣的结构、氧化还原和水氧化性质而被研究。1,2吡啶-2,6-二羧酸(二吡啶酸)已在好氧和厌氧细菌的孢子中被证实。它是在需氧菌孢子萌发时释放的。吡啶-2,6-二羧酸与二价金属离子形成金属配合物,特别是与锰和钙。此外,胍离子在酶中也起着重要作用;例如,x射线结构证据表明,CP43的保守精氨酸357残基的胍离子与光系统II中水氧化配合物(WOC)的Mn 4 Ca簇的距离只有Å几个。合成了标题配合物,并用单晶x射线衍射对其进行了结构表征。该配合物在空间群p1的三斜体系中求解,单位胞参数为:a = 8.5657(4)Å, b = 10.9848(5)Å, c = 13.1681(6)Å, α = 112.617(1)˚,β = 99.646(1)˚,δ = 90.849(1)˚,Z = 2, V = 1123.28(9)Å 3。15675个实测反射的最终R值为R 1 = 0.0344。
Numerous complexes of pyridinecarboxylic acids with transition metals have been investigated because of their interesting structural, redox and water oxidation properties. 1,2 Pyridine-2,6-dicarboxylic (dipicolinic) acid has been demonstrated in spores of aerobic and anaerobic bacteria. It is released during the germination of spores of aerobes. Pyridine-2,6-dicarboxylic forms a metal complex with divalent metal ions, especially with manganese and calcium. 3 Also the guanidinium cation has an important role in enzymes; for example, X-ray structural evidence places the guanidinium cation of the conserved arginine 357 residue of CP43 within a few Å to the Mn 4 Ca cluster of the water-oxidizing complex (WOC) in photosystem II. 4 The title complex was synthesized and structurally characterized by single-crystal X-ray diffraction. This complex was solved in the triclinic system, space group P 1 , with the following unit-cell parameters: a = 8.5657(4)Å, b = 10.9848(5)Å, c = 13.1681(6)Å, α = 112.617(1)˚, β = 99.646(1)˚, δ = 90.849(1)˚, Z = 2, V = 1123.28(9)Å 3 . The final R value was R 1 = 0.0344 for 15675 measured reflections.