绿色化学方法合成cuo纳米结构

IF 1.2 Q4 NANOSCIENCE & NANOTECHNOLOGY international journal of nano dimension Pub Date : 2016-05-01 DOI:10.7508/IJND.2016.02.003
Pourahmad Afshin
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引用次数: 3

摘要

以稻壳灰(RHA)为原料合成了MCM-41分子筛。以摩尔组成sio2: 1.6 EA: 0.215 hdtabr: 325h2o的凝胶为原料,经pH校正,采用室温法制备了 e材料。以十六烷基三甲基溴化铵(CTMABr)为结构模板。采用固相反应合成了Cu含量分别为5.0和10.0 wt.%的纳米复合材料。在400°和600°°c两种不同温度下对样品进行电子煅烧。采用x射线衍射(XRD)、紫外-可见漫反射光谱(UV-Vis DRS)、傅里叶变换红外光谱(FTIR)和透射电子显微镜(TEM)对所制备样品的形貌和理化性质进行了研究。TEM图像显示CuO纳米颗粒尺寸为~ 3 nm。
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GREEN CHEMISTRY APPROACH FOR THE SYNTHESIS OF CUO NANOSTRUCTURE
Molecular sieves MCM-41 were synthesized from rice husk ash (RHA) as alternative sources of silica. e material was synthesized by a room temperature method from a gel with the molar composition SiO 2 : 1.6 EA: 0.215HDTMABr: 325H 2 O with pH correction. The cetyltrimethylammonium bromide (CTMABr) was used as a structure template. Nanocomposite containing 5.0 and 10.0 wt.% of Cu was synthesized under solid state reaction. e calcinations of samples were done at two different temperatures, 400 and 600 ° C. The morphology and the physicochemical properties of the prepared samples were investigated by X-ray diffraction (XRD), UV-Vis diffuse reflectance spectroscopy (UV-Vis DRS), Fourier transform infrared spectroscopy (FTIR) and transmission electron microscopy (TEM). TEM images indicated that nanoparticles size of CuO is ~ 3 nm.
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来源期刊
international journal of nano dimension
international journal of nano dimension NANOSCIENCE & NANOTECHNOLOGY-
CiteScore
2.80
自引率
20.00%
发文量
0
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