浅谈从矿物原料中提取二氧化硅作为吸附剂的前景

D. Mayorov, Yuriy O. Velyaev
{"title":"浅谈从矿物原料中提取二氧化硅作为吸附剂的前景","authors":"D. Mayorov, Yuriy O. Velyaev","doi":"10.30791/1028-978x-2023-2-44-53","DOIUrl":null,"url":null,"abstract":"Samples of amorphous silicon dioxide (SiO2) were obtained by acid decomposition of mineral raw materials (nepheline). Their physico-chemical, acid-base and structural-surface properties have been studied by methods of chemical analysis, Parks, BET, BJH, etc. It was found that in terms of the content of impurities, the pH of the aqueous extract, the pH values of the isoionic point and the zero charge point, the SiO2 samples obtained are almost identical to pyrogenic amorphous silicon dioxide obtained from reactive raw materials (pharmaceutical preparation “Polysorb PM”) and have an increased specific external surface compared to “Polysorb PM” (in 1.1 – 1.9 times) and specific pore volume (1.4 times). Based on the obtained values of the specific capacity of the adsorption monolayer of the surface of SiO2 samples and the change in Gibbs energy (ΔG0) during sorption, it is concluded that the method of their preparation does not significantly affect the physicochemical properties of their surfaces and the mechanism of nitrogen sorption. Based on the results obtained, an assumption is made about the prospects of using silicon dioxide, obtained on the basis of acid processing of mineral raw materials, as an enterosorbent in therapeutic practice.","PeriodicalId":20003,"journal":{"name":"Perspektivnye Materialy","volume":"58 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"On the prospects of using silicon dioxide obtained from mineral raw materials as an enterosorbent\",\"authors\":\"D. Mayorov, Yuriy O. Velyaev\",\"doi\":\"10.30791/1028-978x-2023-2-44-53\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Samples of amorphous silicon dioxide (SiO2) were obtained by acid decomposition of mineral raw materials (nepheline). Their physico-chemical, acid-base and structural-surface properties have been studied by methods of chemical analysis, Parks, BET, BJH, etc. It was found that in terms of the content of impurities, the pH of the aqueous extract, the pH values of the isoionic point and the zero charge point, the SiO2 samples obtained are almost identical to pyrogenic amorphous silicon dioxide obtained from reactive raw materials (pharmaceutical preparation “Polysorb PM”) and have an increased specific external surface compared to “Polysorb PM” (in 1.1 – 1.9 times) and specific pore volume (1.4 times). Based on the obtained values of the specific capacity of the adsorption monolayer of the surface of SiO2 samples and the change in Gibbs energy (ΔG0) during sorption, it is concluded that the method of their preparation does not significantly affect the physicochemical properties of their surfaces and the mechanism of nitrogen sorption. Based on the results obtained, an assumption is made about the prospects of using silicon dioxide, obtained on the basis of acid processing of mineral raw materials, as an enterosorbent in therapeutic practice.\",\"PeriodicalId\":20003,\"journal\":{\"name\":\"Perspektivnye Materialy\",\"volume\":\"58 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2023-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Perspektivnye Materialy\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.30791/1028-978x-2023-2-44-53\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Perspektivnye Materialy","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.30791/1028-978x-2023-2-44-53","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0

摘要

对矿物原料(霞石)进行酸分解制备非晶二氧化硅(SiO2)样品。通过化学分析、Parks、BET、BJH等方法研究了它们的理化性质、酸碱性质和结构表面性质。结果发现,在杂质含量、水萃取物的pH值、等离子点和零电荷点的pH值方面,所获得的SiO2样品与活性原料(药物制剂“Polysorb PM”)所获得的热原非晶二氧化硅几乎相同,并且与“Polysorb PM”相比,具有增加的比外表面(1.1 - 1.9倍)和比孔容(1.4倍)。根据得到的SiO2样品表面吸附单层的比容量和吸附过程中吉布斯能(ΔG0)的变化,得出制备方法对其表面的物理化学性质和氮吸附机理没有显著影响的结论。根据所获得的结果,对二氧化硅作为肠道吸收剂在治疗实践中的应用前景进行了假设。二氧化硅是由矿物原料的酸处理得到的。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
On the prospects of using silicon dioxide obtained from mineral raw materials as an enterosorbent
Samples of amorphous silicon dioxide (SiO2) were obtained by acid decomposition of mineral raw materials (nepheline). Their physico-chemical, acid-base and structural-surface properties have been studied by methods of chemical analysis, Parks, BET, BJH, etc. It was found that in terms of the content of impurities, the pH of the aqueous extract, the pH values of the isoionic point and the zero charge point, the SiO2 samples obtained are almost identical to pyrogenic amorphous silicon dioxide obtained from reactive raw materials (pharmaceutical preparation “Polysorb PM”) and have an increased specific external surface compared to “Polysorb PM” (in 1.1 – 1.9 times) and specific pore volume (1.4 times). Based on the obtained values of the specific capacity of the adsorption monolayer of the surface of SiO2 samples and the change in Gibbs energy (ΔG0) during sorption, it is concluded that the method of their preparation does not significantly affect the physicochemical properties of their surfaces and the mechanism of nitrogen sorption. Based on the results obtained, an assumption is made about the prospects of using silicon dioxide, obtained on the basis of acid processing of mineral raw materials, as an enterosorbent in therapeutic practice.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
自引率
0.00%
发文量
0
期刊最新文献
Effect of synthesis conditions on the physicochemical properties of хerogels, nanopowders and ceramic materials in the CeO2 – Nd2O3 system Influence of 3D-printing parameters on mechanical properties of polyethylene terephthalate glycol (PET-G) products Laser-ultrasonic study of local porosity distribution in CFRP stringer panels Potentiodynamic study of lead babbit BLa (PbSb15Sn10), with lanthanum, in the electrolyte environment NaCl Effect of low-temperature plasma treatment on polyketon films: changes in the chemical structure and surface morphology
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1