M. Viczián, I. Cornides, J. Van Puymbroeck, R. Gijbels
{"title":"火花源质谱法的时间分辨测量。1、离子束偏转","authors":"M. Viczián, I. Cornides, J. Van Puymbroeck, R. Gijbels","doi":"10.1016/0020-7381(83)85030-X","DOIUrl":null,"url":null,"abstract":"<div><p>The synchronous passer system of a JEOL spark source mass spectrometer was modified so that the ion beam could be deflected at a variable time after the start of the first of a series of discharges. The transmitted part of the ion beam was analyzed by photoplate detection.</p><p>Time-resolved measurements revealed a different behaviour between different ionic species of the same <em>m/z</em> value. The singly-charged atomic ions were delayed by (150±100) ns with respect to the multiply-charged ions. Molecular ions were found to be delayed by about 700 ns (C<sub><em>n</em></sub><sup>+</sup>) or even one or more μs (S<sub><em>n</em></sub><sup>+</sup>, SC<sub><em>n</em></sub><sup>+</sup>) relative to multiply-charged ions.</p><p>The duration of the production/extraction process of multiply- and singly-charged ions was well defined in time, while this process could last for several μs in the case of polyatomic ions.</p></div>","PeriodicalId":13998,"journal":{"name":"International Journal of Mass Spectrometry and Ion Physics","volume":"51 1","pages":"Pages 77-92"},"PeriodicalIF":0.0000,"publicationDate":"1983-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0020-7381(83)85030-X","citationCount":"10","resultStr":"{\"title\":\"Time-resolved measurements in spark source mass spectrometry. I. Deflection of the ion beam\",\"authors\":\"M. Viczián, I. Cornides, J. Van Puymbroeck, R. Gijbels\",\"doi\":\"10.1016/0020-7381(83)85030-X\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The synchronous passer system of a JEOL spark source mass spectrometer was modified so that the ion beam could be deflected at a variable time after the start of the first of a series of discharges. The transmitted part of the ion beam was analyzed by photoplate detection.</p><p>Time-resolved measurements revealed a different behaviour between different ionic species of the same <em>m/z</em> value. The singly-charged atomic ions were delayed by (150±100) ns with respect to the multiply-charged ions. Molecular ions were found to be delayed by about 700 ns (C<sub><em>n</em></sub><sup>+</sup>) or even one or more μs (S<sub><em>n</em></sub><sup>+</sup>, SC<sub><em>n</em></sub><sup>+</sup>) relative to multiply-charged ions.</p><p>The duration of the production/extraction process of multiply- and singly-charged ions was well defined in time, while this process could last for several μs in the case of polyatomic ions.</p></div>\",\"PeriodicalId\":13998,\"journal\":{\"name\":\"International Journal of Mass Spectrometry and Ion Physics\",\"volume\":\"51 1\",\"pages\":\"Pages 77-92\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1983-06-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0020-7381(83)85030-X\",\"citationCount\":\"10\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Mass Spectrometry and Ion Physics\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/002073818385030X\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Mass Spectrometry and Ion Physics","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/002073818385030X","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Time-resolved measurements in spark source mass spectrometry. I. Deflection of the ion beam
The synchronous passer system of a JEOL spark source mass spectrometer was modified so that the ion beam could be deflected at a variable time after the start of the first of a series of discharges. The transmitted part of the ion beam was analyzed by photoplate detection.
Time-resolved measurements revealed a different behaviour between different ionic species of the same m/z value. The singly-charged atomic ions were delayed by (150±100) ns with respect to the multiply-charged ions. Molecular ions were found to be delayed by about 700 ns (Cn+) or even one or more μs (Sn+, SCn+) relative to multiply-charged ions.
The duration of the production/extraction process of multiply- and singly-charged ions was well defined in time, while this process could last for several μs in the case of polyatomic ions.
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