ÃÂ5甾体化合物烯丙基氧化制烯酮方法综述

Journal of steroids & hormonal science Pub Date : 2016-04-02 DOI:10.4172/2157-7536.1000171

Wendell Sg, Edwards Jp

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引用次数: 4

摘要

α， β-不饱和酮的引入改变了Δ5甾体烯烃化合物的特性和生物学功能。已经报道了几种合成方法来完成Δ5甾体烯烃羰基的引入。在这里，这篇简短的综述将列出许多氧化方法，特别是那些通过过氧化物中间体和/或使用铬配合物作为试剂的氧化方法。

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A Short Review of Methods for the Allylic Oxidation of ÃÂ5 SteroidalCompounds to Enones

Introduction of α, β-unsaturated ketones to Δ5 steroidal olefins changes the characteristics and biological function of those compounds. Several synthetic methods have been reported to accomplish carbonyl introduction to Δ5 steroidal olefins. Herein, this short review will catalogue many of those oxidative methods, particularly those proceeding through a peroxide intermediate and/or use chromium complexes as reagents.

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Journal of steroids & hormonal science

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