离子交换树脂在酸性溶液中去除硫酸盐离子的应用

M. Holub, P. Pavlíková, M. Bálintová, M. Smolakova
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引用次数: 2

摘要

从不同类型的废水中去除硫酸盐离子是采矿,石化或冶金工业等几个工业部门面临的环境挑战。目前现有的大多数选择都效率低下,经济上也不可行,特别是酸性矿井排水(AMD),其中低pH值和高浓度的重金属和硫酸盐限制了这些过程。本工作的重点是离子交换作为AMD治疗的最常见的治疗方法之一。离子交换是一种非常强大的技术,通过与另一种物质交换,将一种或多种不需要的污染物从水环境中去除。硫酸盐还原的理想离子交换溶液是阴离子和阳离子树脂的结合。本文介绍了用合成离子交换树脂和AMBERLITE MB20对模型溶液中so42 -进行离子交换实验的结果。AMBERLITE MB20树脂对模型溶液h2so4的去除率高于PUROLITE MB400树脂,随着硫酸盐浓度的增加,其去除率从100 mg/L的86.6%下降到1000 mg/L的66.9%。DOI: http://dx.doi.org/10.5755/j01.ct.68.1.15004
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APPLICATION OF ION-EXCHANGE RESINS FOR REMOVING SULPHATE IONS FROM ACIDIC SOLUTIONS
The removal of sulphate ions from different types of wastewater is an environmental challenge faced by several industrial sectors such as the mining, petrochemical or metallurgical industry. Most of the current existing options are inefficient and economically unviable, particularly for acid mine drainage (AMD), where the low pH and high concentrations of heavy metals and sulphates are limiting for these processes. This work is focused on ion-exchange as one of the most common treatment methods for AMD treatment. Ion-exchange represents a very powerful technology where one or more undesirable contaminants are removed from the aqueous environment by exchange with another substance. The ideal ion-exchange solution for sulphate reduction is one that combines both anionic and cationic resins. The paper presents the results from ion-exchange experiments by the synthetic ion-exchange resin and the AMBERLITE MB20 for SO 4 2– removal from a model solution. The efficiency of the AMBERLITE MB20 resin for SO 4 2– removal from the model solution H 2 SO 4 was higher than of the PUROLITE MB400, and its efficiency decreased with increasing the concentration of sulphates from 86.6 % for the concentration 100 mg/L to 66.9 % for the concertation 1000 mg/L. DOI: http://dx.doi.org/10.5755/j01.ct.68.1.15004
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