核桃壳纳米多孔碳材料的结构与吸附性能

IF 0.9 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Physics and Chemistry of Solid State Pub Date : 2023-06-25 DOI:10.15330/pcss.24.2.348-353
S. A. Lisovska, R.V. Ilnytskyy, R. Lisovskyy, N. Ivanichok, K. Bandura, B. Rachiy
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引用次数: 1

摘要

采用低温氮吸附/解吸的方法,对轻工业废料(核桃壳)碱活化后进行热改性制备的纳米多孔碳材料的孔隙结构进行了研究。建立了温度与改性时间的最佳关系。结果表明,改性温度的升高缩短了微孔向中孔转变的时间,导致比表面积和总孔容的减小。因此,改性温度为400℃,保温时间为120 min时得到的材料的最大比表面积为940 m2/g。研究表明,温度改性时间的增加会导致比电导率的增加。
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Structural and sorption properties of nanoporous carbon materials obtained from walnut shells
Using the method of low-temperature nitrogen adsorption/desorption, the porous structure of nanoporous carbon materials obtained by alkaline activation of light industry waste (walnut shells) with subsequent thermal modification was investigated. The optimal relationship between temperature and modification time has been established. It is shown that an increase in the modification temperature reduces the transition time of micropores into mesopores and leads to a decrease in the specific surface area and total pore volume. Thus, the material obtained at a modification temperature of 400 ºC and a holding time of 120 min is characterized by the maximum specific surface area of 940 m2/g. It has been investigated that an increase in the time of temperature modification leads to an increase in specific electrical conductivity.
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CiteScore
1.70
自引率
14.30%
发文量
83
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