{"title":"具有二维+二维→三维聚catenated结构的柔性羧酸盐与刚性咪唑配体构建的新型Zn(II)配位聚合物","authors":"Xiuling Feng, Wanping Chen, B. Xiang","doi":"10.1080/15533174.2015.1004453","DOIUrl":null,"url":null,"abstract":"A new Zn (II) coordination polymer with benzophenone-4,4′-dicarboxylic acid (H2bpdc) and 1,4-bis(imidazol-1-yl)benzene (bib) has been prepared by hydrothermal synthesis and characterized by single-crystal X-ray diffraction, IR, and EA. Complex, {[Zn(bpdc) (bib)]·2H2O}n(1), is triclinic, space group P-1 with a = 8.958(5), b = 11.336(5), c = 14.150(5) Å,α = 111.109(5), β = 95.077 (5)° γ = 98.504(5), V = 1310.0 (10) Å3, Z = 2, Mr = 579.86, Dc = 1.470 g/cm3, F(000) = 596, and µ = 0.991 mm−1. The final refinement gave R = 0.0352 and wR = 0.0964 for 5191 reflections with I > 2σ(I). X-ray diffraction analysis reveals that the complex 1 displays a 2D+2D→3D polycatenated structure.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2016-04-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"A New Zn(II) Coordination Polymer Constructed by Flexible Carboxylate and Rigid Imidazole-Containing Coligands With a 2D+2D→3D Polycatenated Structure\",\"authors\":\"Xiuling Feng, Wanping Chen, B. Xiang\",\"doi\":\"10.1080/15533174.2015.1004453\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A new Zn (II) coordination polymer with benzophenone-4,4′-dicarboxylic acid (H2bpdc) and 1,4-bis(imidazol-1-yl)benzene (bib) has been prepared by hydrothermal synthesis and characterized by single-crystal X-ray diffraction, IR, and EA. Complex, {[Zn(bpdc) (bib)]·2H2O}n(1), is triclinic, space group P-1 with a = 8.958(5), b = 11.336(5), c = 14.150(5) Å,α = 111.109(5), β = 95.077 (5)° γ = 98.504(5), V = 1310.0 (10) Å3, Z = 2, Mr = 579.86, Dc = 1.470 g/cm3, F(000) = 596, and µ = 0.991 mm−1. The final refinement gave R = 0.0352 and wR = 0.0964 for 5191 reflections with I > 2σ(I). X-ray diffraction analysis reveals that the complex 1 displays a 2D+2D→3D polycatenated structure.\",\"PeriodicalId\":22118,\"journal\":{\"name\":\"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2016-04-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1080/15533174.2015.1004453\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/15533174.2015.1004453","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
A New Zn(II) Coordination Polymer Constructed by Flexible Carboxylate and Rigid Imidazole-Containing Coligands With a 2D+2D→3D Polycatenated Structure
A new Zn (II) coordination polymer with benzophenone-4,4′-dicarboxylic acid (H2bpdc) and 1,4-bis(imidazol-1-yl)benzene (bib) has been prepared by hydrothermal synthesis and characterized by single-crystal X-ray diffraction, IR, and EA. Complex, {[Zn(bpdc) (bib)]·2H2O}n(1), is triclinic, space group P-1 with a = 8.958(5), b = 11.336(5), c = 14.150(5) Å,α = 111.109(5), β = 95.077 (5)° γ = 98.504(5), V = 1310.0 (10) Å3, Z = 2, Mr = 579.86, Dc = 1.470 g/cm3, F(000) = 596, and µ = 0.991 mm−1. The final refinement gave R = 0.0352 and wR = 0.0964 for 5191 reflections with I > 2σ(I). X-ray diffraction analysis reveals that the complex 1 displays a 2D+2D→3D polycatenated structure.
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