液体中脉冲激光烧蚀制备(Au@Pt)超细纳米颗粒的合成与表征

A. Nasria, S. Thahab, S. Hussain
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摘要

采用(q -开关,1064倍频- nd: YAG)脉冲激光烧蚀液体法制备了金(Au)、铂(Pt)和金包覆铂(Au@Pt)超细(UF)纳米粒子。激光烧蚀Au,Pt金属板和(Au@Pt)通过将这些金属板浸泡在两种不同的液体去离子水(DIW)和乙醇中进行。(PLAL)工艺以100脉冲能量700mj,液体深度2cm进行。金元素的纳米颗粒被铂(Au@Pt)包裹在两个步骤中。首先检查金元素的纳米管,然后从第一步开始将铂金属浸入液体中。用吸收光谱峰来量化PLAL工艺的形成效率。DIW的吸收光谱(Pt)在234nm左右呈尖峰单峰,(Au@Pt)在516nm和221nm处呈尖峰单峰。透射电镜图像显示,纳米颗粒呈球形,平均粒径在(2 ~ 5)nm之间,加入乙醇后,纳米颗粒的粒径有所增大。改变流体环境的方式是控制Au、Pt和(Au@Pt)的尺寸和强度的一种简单而灵活的方法。
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Synthesized and Characterizing of (Au@Pt) Ultra Fine Nanoparticles Prepared by Pulsed Laser Ablation in Liquids
Gold(Au), Platium (Pt) and Gold –Coated Platinum (Au@Pt) ultra Fine(UF) nanoparticles (NPs) were preperd by Pulsed Laser Ablation in Liquids method with (Q-switched, 1064 doubled frequency-Nd: YAG). The laser ablation of Au ,Pt metal plates and (Au@Pt) has been performed by immersing these metal plates in two different liquid deionised water (DIW) and ethanol alcohol . (PLAL) process preformed with 100 pulse energy of 700 mJ and liquid depth is 2cm. The nanoparticles of the gold element were coated with platinum(Au@Pt) in two steps. The nanotubes of the gold element were first examined and the platinum metal was then immersed in the liquid from the first step. The formation efficiency of PLAL process was quantified in term of the absorption spectrum peaks. The absorption spectra ( Pt) in DIW shows a sharp and single peak around 234nm,and (Au@Pt) shows a sharp and single peak for Au at 516nm and for Pt 221nm.The TEM images show that the nanoparticles are rather spherical in shape .While the average size for all the samples was in rang from(2-5)nm .There was an increase in size when using ethanol alcohol. Changing the way of the fluid environment is a simple and flexible way to control the size and strength of Au and Pt and (Au@Pt)
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