粘土-生物炭复合材料去除水中镉离子

M. Omar, N. Njomo, A. O. Yusuf, I. Michira
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摘要

本文报道了以普通粘土和豆豆生物材料为原料合成纳米复合材料的生物炭材料,用于去除水中镉离子的研究。将普通粘土与拟南豆生物材料在500℃温度下加热制备复合材料,并通过XRF、EDX、FTIR、XRD和SEM对合成物进行表征。表征材料的结果表明,黏土矿物成功地渗透到生物炭材料表面形成复合材料。采用间歇吸附法测定了复合材料对镉金属的去除效果。复合材料对镉离子的去除率达到99%。采用Freundlich吸附等温线和Langmuir吸附等温线对水中镉离子的去除效果进行了研究,相关系数r2分别为0.924和0.932。结果还揭示了镉离子去除的伪二级反应。
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Composite Material of Clay-biochar for Cadmium Ion Removal from Water
A research study of the synthesis of nanocomposite of clay-biochar material acquired from normal clay and biomaterial of Prosopis Juliflora for cadmium ion removal from aqueous solutions is reported. Composite materials were prepared by heating of ordinary clay and biomaterial of Prosopis at 500°C temperature and the synthesis was established with XRF, EDX, FTIR, XRD and SEM characterization. The results of characterized material showed that clay minerals successfully permeated the surface of biochar materials to form composites. The effectiveness of the composites in removing cadmium metal was determined by a batch adsorption procedure. The composite material produced a removal efficiency of 99% of cadmium ions. Adsorption was investigated using the adsorption isotherms of Freundlich and Langmuir which showed correlation r2 values of 0.924 and 0.932 respectively for the removal of cadmium ions from water. The results also revealed a pseudo second-order reaction for cadmium ions removal.
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