新型单相白色荧光粉Gd7O6(BO3)(PO4)2:Dy3+

Rongli Zhao, Xiang Guo, Yi Ling, Ruirui Cui
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引用次数: 0

摘要

采用高温固相法合成了一系列Gd7O6(BO3)(PO4)2:xDy3+荧光粉。用X射线衍射仪和光谱仪分析了荧光粉的相位和光谱特性。发现电偶极子与磁偶极子对应的光强之比可以调节光致发光的颜色,最优浓度x = 0.05达到1.0834,非常接近白光。这种现象与晶格的对称性有关。同时,观察到荧光衰减寿命随浓度的增加而减小。从样品的测量颜色得到的国际发光委员会坐标也非常接近标准白光坐标(0.3333,0.3333)。上述结果表明,Gd7O6(BO3)(PO4)2:xDy3+是下一代白光发光二极管的理想候选材料。
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A Novel Single‐Phase White Phosphor Gd7O6(BO3)(PO4)2:Dy3+
A series of Gd7O6(BO3)(PO4)2:xDy3+ phosphors are synthesized using high‐temperature solid‐phase method. The phase and spectral characteristics of phosphors are analyzed using X‐ray diffraction and spectrometer. It is found that the ratio of the light intensity corresponding to the electric dipole and magnetic dipole can regulate the color of the photoluminescence, and the optimal concentration x = 0.05 reaches 1.0834, which is very close to white light. This phenomenon is related to the symmetry of the lattice. Simultaneously, it is observed that the fluorescence decay lifetime decreases with increasing concentration. The Commission Internationale de l'Eclairage coordinates obtained from the measured color of the sample are also very close to the standard white light coordinates (0.3333, 0.3333). The results presented above suggest that Gd7O6(BO3)(PO4)2:xDy3+ is a promising candidate for the next generation of white light‐emitting diodes.
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