硫铝酸钙白石水泥的水灰比:水化、凝结时间和强度发展

Lisa E. Burris , Kimberly E. Kurtis
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引用次数: 11

摘要

很少有公开的数据可以指导工程师设计具有足够和易性、强度和耐久性的硫铝酸钙白石(CSAB)水泥混合物。缺乏对设计因素的理解,特别是w/c变化的影响,是CSAB广泛使用的一个重大障碍。本研究对w/c为0.3 - 0.6的两种CSAB水泥的水化、凝结时间和强度发展进行了评价。CSAB反应动力学随CSAB组成(特别是硫酸钙含量)的增加而变化,随着w/c的增加,高硬石膏/无水石膏含量的水泥的缓速增加,而低硬石膏/无水石膏含量的水泥的缓速减少。对于这两种水泥,更高的w/c会导致更大的总水化,增加凝结时间,降低膏体和砂浆样品的抗压强度。凝固时间与硬石膏含量的关系比w/c更密切,硫酸盐体积的增加缩短了凝固时间。
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Water-to-cement ratio of calcium sulfoaluminate belite cements: Hydration, setting time, and strength development

Little published data is available to guide engineers in designing calcium sulfoaluminate belite (CSAB) cement mixtures with adequate workability, strength, and durability. This lack of understanding of design factors, especially the effect of varying w/c, represents a significant barrier to widespread CSAB use. In this study hydration, setting time, and strength development of two CSAB cements with w/c from 0.3 – 0.6 were evaluated. CSAB reaction kinetics varied with increased w/c depending on CSAB composition, specifically calcium sulfate content – with higher w/c increasing retardation in higher anhydrite/ye'elimite content cement, but reduced retardation in lower anhydrite/ye'elimite cement. For both cements, greater w/c led to greater total hydration, increased setting times, and reduced compressive strengths in the pastes and mortar samples. Setting time was linked more closely to anhydrite content than w/c, with greater sulfate volumes shortening setting times.

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