二苯基亚砜铬三羰基的区域选择性邻位取代:对单阴离子和二阴离子的互补立体选择性

S. Davies, Tracey Loveridge, J. Clough
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引用次数: 18

摘要

由二苯基亚砜、三羰基铬和二异丙酰胺锂衍生的单阴离子和二阴离子在与亲电试剂(D+、MeI、Me3SiCl)的反应中表现出互补的立体选择性。
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Regioselective ortho substitution of diphenyl sulfoxide chromium tricarbonyl: complementary stereoselectivities for the mono- and di-anions
The mono- and di-anions derived from diphenyl sulfoxide chromium tricarbonyl and lithium diisopropylamide show complementary Stereoselectivities in their reactions with electrophiles (D+, MeI, Me3SiCl).
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