含黄原胶琼脂凝胶中l -谷氨酸、钠离子和d -葡萄糖的扩散分析

K. Tayama, Y. Okamoto, H. Hashiba
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摘要

研究了调味料(l-谷氨酸、钠离子和d-葡萄糖)在凝胶中的扩散过程。在本研究中,将凝胶浸泡在含有0.30%(W/V)味精、1.0% (W/V) NaCl和/或3.0%(W/ V) D -葡萄糖的溶液中,在含黄原胶(0%、0.20%或0.50% (W/W))的2.0% (W/W)琼脂凝胶中,在30℃一维扩散体系中,测定24小时的表观扩散系数(D)。结果表明,在含有黄原胶的琼脂凝胶中,NaCl的存在使l-谷氨酸的D升高,但再加入D -葡萄糖,这种升高作用消失。添加黄原胶对钠离子D的增加也被添加D -葡萄糖所抑制。可见,黄原胶中的羧基有利于钠离子的扩散,l-谷氨酸的扩散随着钠离子的流动而增加。
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Analysis of diffusion of L-glutamic acid, sodium ions and D-glucose in agar gel containing xanthan gum
We studied the diffusion processes of seasoning materials (l-glutamic acid, sodium ion and d-glucose) in gels. In the present study, the gel was soaked in a solution containing 0.30%(W/V) monosodium glutamate, 1.0% (W/V) NaCl and/or 3.0%(W/ V) d-glucose, and the apparent diffusion coefficient (D) was determined in 2.0% (W/ W) agar gel containing xanthan gum ( 0 %, 0.20% or 0.50% (W/W)) after 24 hr at 30 °C in a one-dimensional diffusion system. As the results, the D of l-glutamic acid increased in the presence of NaCl in the agar gel containing xanthan gum, but the increasing effect disappeared by the further addition of d-glucose. The increase in D of sodium ion by the addition of xanthan gum was also suppressed by the addition of d-glucose. It was obvious that the dif fusion of sodium ions was facilitated by the carboxyl-group in the xanthan gum, and that the diffusion of l-glutamate increased with the flow of the sodium ions.
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