A. Echavarren, Michael E Muratore, Verónica López‐Carrillo, Ana Escribano-Cuesta, N. Huguet, C. Obradors
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Gold‐Catalyzed Cyclizations of Alkynes with Alkenes and Arenes
This chapter reviews the gold-catalyzed cyclization reactions of alkynes with alkenes that proceed via selective activation of the alkyne by π-coordination of the transition metal. Mechanistically related intermolecular reactions between alkynes and alkenes are also discussed, as are reactions of alkynes with arenes, heteroarenes, and related nucleophiles.
Keywords:
gold;
alkynes;
alkenes;
cyclizations;
skeletal rearrangements;
metal carbenes
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