聚苯乙烯溶液的瑞利散射

N. Ford, F. E. Karasz, J. Owen
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引用次数: 26

摘要

用激光同差光谱仪研究了聚苯乙烯+ 2-丁酮稀溶液散射光的功率谱。根据测量结果,确定了大分子的平移扩散常数作为分子量和溶质浓度的函数。对数据的分析包括对聚合物的未扰动尺寸的估计。
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Rayleigh scattering from polystyrene solutions
A laser homodyne spectrometer has been used to study the power spectrum of light scattered from dilute polystyrene + 2-butanone solutions. From the measurements the translational diffusion constants for the macromolecules were determined as a function of molecular weight and solute concentration. The analysis of the data included an estimation of the unperturbed dimensions of the polymer.
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