{"title":"两种4-氯苯磺酰甘氨酸配体过渡金属配合物的合成、晶体结构和热性能","authors":"Zheng-Jun Liu, Xiao-Miao Chen, S. Hao, M. Cheng","doi":"10.1080/15533174.2014.988810","DOIUrl":null,"url":null,"abstract":"Two new transition metal complexes [Cu(4-Cbsgly)(phen)]·0.5H2O (1), [Ni(4-Cbsgly)(phen)2]·3H2O (2) [4-CbsglyH2 = (4-chlorobenzenesulfonyl-glycine acid, phen = 1,10-phenanthroline) were synthesized and characterized by elemental analysis, IR, TG analysis, and single-crystal X-ray diffraction. The complexes 1 and 2 are assembled by various kinds of hydrogen bonds and π-π stacking interactions into the 1D chain and 2D layer, respectively. Two-dimensional layer in 2 are further connected to form sandwich-like structure through weak O–H···O and C–H···O interactions. Furthermore, the thermal stability of complexes 1 and 2 were investigated.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2016-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"5","resultStr":"{\"title\":\"Syntheses, Crystal Structures, and Thermal Properties of Two Transition Metal Complexes With 4-Chlorobenzenesulfonyl-glycine Acid Ligand\",\"authors\":\"Zheng-Jun Liu, Xiao-Miao Chen, S. Hao, M. Cheng\",\"doi\":\"10.1080/15533174.2014.988810\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Two new transition metal complexes [Cu(4-Cbsgly)(phen)]·0.5H2O (1), [Ni(4-Cbsgly)(phen)2]·3H2O (2) [4-CbsglyH2 = (4-chlorobenzenesulfonyl-glycine acid, phen = 1,10-phenanthroline) were synthesized and characterized by elemental analysis, IR, TG analysis, and single-crystal X-ray diffraction. The complexes 1 and 2 are assembled by various kinds of hydrogen bonds and π-π stacking interactions into the 1D chain and 2D layer, respectively. Two-dimensional layer in 2 are further connected to form sandwich-like structure through weak O–H···O and C–H···O interactions. Furthermore, the thermal stability of complexes 1 and 2 were investigated.\",\"PeriodicalId\":22118,\"journal\":{\"name\":\"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2016-04-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"5\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1080/15533174.2014.988810\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/15533174.2014.988810","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Syntheses, Crystal Structures, and Thermal Properties of Two Transition Metal Complexes With 4-Chlorobenzenesulfonyl-glycine Acid Ligand
Two new transition metal complexes [Cu(4-Cbsgly)(phen)]·0.5H2O (1), [Ni(4-Cbsgly)(phen)2]·3H2O (2) [4-CbsglyH2 = (4-chlorobenzenesulfonyl-glycine acid, phen = 1,10-phenanthroline) were synthesized and characterized by elemental analysis, IR, TG analysis, and single-crystal X-ray diffraction. The complexes 1 and 2 are assembled by various kinds of hydrogen bonds and π-π stacking interactions into the 1D chain and 2D layer, respectively. Two-dimensional layer in 2 are further connected to form sandwich-like structure through weak O–H···O and C–H···O interactions. Furthermore, the thermal stability of complexes 1 and 2 were investigated.
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