{"title":"三配位锌阳离子的合成及其催化活性","authors":"Mark D. Hannant, M. Schormann, M. Bochmann","doi":"10.1039/B208165M","DOIUrl":null,"url":null,"abstract":"Reaction between DADZnR2 and either B(C6F5)3 or ZnR2 and [DADH][B(C6F5)4] affords three-coordinate alkyl and amide zinc cations which are active for the ring opening polymerisation of epoxides and e-caprolactone [DAD = \n(MeCNC6H3Pri2-2,6)2].","PeriodicalId":17317,"journal":{"name":"Journal of The Chemical Society-dalton Transactions","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2002-11-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"69","resultStr":"{\"title\":\"Synthesis and catalytic activity of three-coordinate zinc cations\",\"authors\":\"Mark D. Hannant, M. Schormann, M. Bochmann\",\"doi\":\"10.1039/B208165M\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Reaction between DADZnR2 and either B(C6F5)3 or ZnR2 and [DADH][B(C6F5)4] affords three-coordinate alkyl and amide zinc cations which are active for the ring opening polymerisation of epoxides and e-caprolactone [DAD = \\n(MeCNC6H3Pri2-2,6)2].\",\"PeriodicalId\":17317,\"journal\":{\"name\":\"Journal of The Chemical Society-dalton Transactions\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2002-11-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"69\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society-dalton Transactions\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/B208165M\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society-dalton Transactions","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/B208165M","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Synthesis and catalytic activity of three-coordinate zinc cations
Reaction between DADZnR2 and either B(C6F5)3 or ZnR2 and [DADH][B(C6F5)4] affords three-coordinate alkyl and amide zinc cations which are active for the ring opening polymerisation of epoxides and e-caprolactone [DAD =
(MeCNC6H3Pri2-2,6)2].
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