阴极电沉积过程中有机膜生长动力学研究

V.B. Mišković, M.D. Maksimović
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引用次数: 11

摘要

采用恒流法和恒压法研究了阴极电沉积过程中有机膜生长的动力学和机理。在较低电压下进行的恒压实验能够更准确地观察到电流密度的变化,并能够提出一个数学模型,该模型给出了薄膜生长动力学的一致图像。结果表明,薄膜厚度随时间的增加而增加,但没有达到一个极限值。
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The kinetics of organic film growth during the cathodic electrodeposition process

The kinetics and the mechanism of organic film growth during the cathodic electrodeposition process are investigated by galvanostatic and constant voltage methods. Constant voltage experiments carried out at lower voltages enabled the more accurate observation of current density changes and enabled the proposal of a mathematical model which gives a consistent picture of film growth kinetics. It was shown that the film thickness increases with time but a limiting value was not achieved.

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