辐射对纳米结构聚苯胺/Bi2Te3复合材料导热性能的影响。

M. Shalaby, N. Yousif, H. Zayed, H. Hashem, L. Wahab
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引用次数: 4

摘要

采用溶剂热法合成了纳米结构Bi2Te3、聚苯胺(PANI)和PANI/ Bi2Te3。利用Win fit和unit cell软件对x射线衍射(XRD)结果计算了晶体尺寸、应变、链间分离和单元胞体积。剂量为50 KGy的γ射线辐照对聚苯胺样品的峰位有影响;它影响Bi2Te3样品的强度。采用差示扫描量热仪(DSC)对铟(In)熔化温度曲线进行了热导率测量。50 KGy剂量后,PANI和PANI/ Bi2Te3值变化不明显,而Bi2Te3值降低。
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The effect of Radiation on Thermal conductivity of Nano-Structured PANI/Bi2Te3 Composites.
Nano-structured Bi2Te3, Polyaniline (PANI) and PANI/ Bi2Te3 were synthesized by Solvothermal method. The crystallite size, Strain, inter-chain separation and unit cell volume were calculated from the X-ray diffraction (XRD) results by using Win fit and Unit cell software. The Gamma irradiation (γ-rays) with dose 50 KGy affects the peaks positions for the PANI samples whereas; it affects the intensity of Bi2Te3 samples. Thermal conductivity measurements were investigated from the differential scanning calorimeter (DSC) with respect to Indium (In) melting temperature curve. 50 KGy dose does not show a remarkable change in the PANI and PANI/ Bi2Te3 values on contrast the value of Bi2Te3 sample was reduced.
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