{"title":"负载氟离子与气态硫芥子气的反应","authors":"Anthony J. Bellamy","doi":"10.1016/0923-1137(94)90007-8","DOIUrl":null,"url":null,"abstract":"<div><p>The behaviour of supported fluoride ion when treated with gaseous sulphur mustard, (ClCH<sub>2</sub>CH<sub>2</sub>)<sub>2</sub>S, has been studied. Amberlyst A-26 F<sup>−</sup> was found to have a large capacity for reaction (1.5 mmol S-mustard/g resin), the only observed organic product being divinyl sulphide. Fluoride ion on other support materials showed much lower reaction capacity.</p></div>","PeriodicalId":20864,"journal":{"name":"Reactive Polymers","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1994-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0923-1137(94)90007-8","citationCount":"12","resultStr":"{\"title\":\"Reaction of supported fluoride ion with gaseous sulphur mustard\",\"authors\":\"Anthony J. Bellamy\",\"doi\":\"10.1016/0923-1137(94)90007-8\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The behaviour of supported fluoride ion when treated with gaseous sulphur mustard, (ClCH<sub>2</sub>CH<sub>2</sub>)<sub>2</sub>S, has been studied. Amberlyst A-26 F<sup>−</sup> was found to have a large capacity for reaction (1.5 mmol S-mustard/g resin), the only observed organic product being divinyl sulphide. Fluoride ion on other support materials showed much lower reaction capacity.</p></div>\",\"PeriodicalId\":20864,\"journal\":{\"name\":\"Reactive Polymers\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1994-10-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0923-1137(94)90007-8\",\"citationCount\":\"12\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Reactive Polymers\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0923113794900078\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Reactive Polymers","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0923113794900078","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 12
摘要
研究了负载氟离子在气态硫芥(ClCH2CH2)2S处理下的行为。Amberlyst a - 26f -具有较大的反应能力(1.5 mmol S-mustard/g resin)，唯一观察到的有机产物是二乙烯基硫化物。氟离子在其他载体材料上的反应能力较低。
Reaction of supported fluoride ion with gaseous sulphur mustard
The behaviour of supported fluoride ion when treated with gaseous sulphur mustard, (ClCH2CH2)2S, has been studied. Amberlyst A-26 F− was found to have a large capacity for reaction (1.5 mmol S-mustard/g resin), the only observed organic product being divinyl sulphide. Fluoride ion on other support materials showed much lower reaction capacity.
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