2‐乙酰萘[2,1‐b]呋喃肟与2‐苯甲酰萘[2,1‐b]呋喃肟金属配合物的比较研究

K. Latha, V. Vaidya, J. Keshavayya
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引用次数: 2

摘要

摘要合成了2‐乙酰萘[2,1‐b]呋喃肟(L1)和2‐苯甲酰萘[2,1‐b]呋喃肟(L2)与金属离子Cu(II)、Ni(II)、Co(II)、Cd(II)和Hg(II)的配合物,并通过元素分析、电导、磁化率测量、热重分析、粉末x射线衍射、核磁共振、紫外电子和红外光谱研究对其进行了表征。通过核磁共振和红外光谱数据推导了配体原子与金属离子的配位。磁性研究揭示了配合物的结构。通过热分析研究了配合物的稳定性。这些配合物的粉末x射线衍射研究表明,它们本质上是结晶的。所有的配合物、配体和金属盐都经过了抗菌、驱虫药和镇痛活性的筛选。
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Comparative Studies on Metal Complexes of 2‐Acetylnaphtho[2,1‐b]furan Oxime and 2‐Benzoylnaphtho[2,1‐b]furan Oxime
Abstract The complexes of two new ligands, 2‐acetylnaphtho[2,1‐b]furan oxime (L1) and 2‐benzoylnaphtho[2,1‐b]furan oxime (L2), with the metal ions Cu(II), Ni(II), Co(II), Cd(II), and Hg(II) have been synthesized and characterized on the basis of elemental analyses, conductance, magnetic susceptibility measurements, TGA, powder x‐ray diffraction, NMR, UV‐electronic, and IR spectral studies. Coordination of the ligand atoms to the metal ion was deduced by NMR and IR spectral data. Magnetic studies revealed the structures of the complexes. The stability of the complexes was studied by thermal analysis. Powder x‐ray diffraction studies of the complexes have shown that they are crystalline in nature. All the complexes, ligands and metal salts have been screened for antimicrobial, anthelmintic, and analgesic activities.
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