可靠的钙钛矿光伏组件额定功率

Tao Song, L. Ottoson, Josh Gallon, D. Friedman, N. Kopidakis
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引用次数: 2

摘要

随着钙钛矿技术的商业化,大尺寸钙钛矿组件的可靠和准确的额定功率成为其未来在光伏市场部署的一个突出方面。众所周知,由于钙钛矿光伏器件在传统的电流-电压(IV)测量过程中具有复杂的动态响应,因此其性能校准非常具有挑战性。光伏研究人员之前提出了几种稳态性能校准方法来可靠地提取光伏效率,但大多集中在小面积研究型电池上。在本文中,我们强调了可靠的性能校准对大尺寸钙钛矿模块的重要性。将NREL电池和模块性能(CMP)小组的钙钛矿电池稳态性能校准协议(即渐近PMAX扫描)扩展到模块,我们证明了报告钙钛矿电池稳态效率的必要性,并讨论了将该协议应用于模块的挑战。我们还提出了最大功率点跟踪(MPPT)协议,这是一种经常用于钙钛矿电池和模块性能校准的技术,并展示了MPPT和渐近PMAX之间的比较。使用MPPT,我们展示了钙钛矿模块中亚稳态和降解之间的相互作用,并强调了开发稳定这些器件的预处理协议的必要性。我们的目标是促进钙钛矿组件性能校准的共识协议的发展,并提高其可靠的额定功率,这将有利于钙钛矿技术在光伏市场的发展。
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Reliable Power Rating of Perovskite PV Modules
As the perovskite technology is ramping up into commercialization, reliable and accurate power rating of large-size perovskite modules becomes a prominent aspect for its future deployment in the PV market. It is known that the performance calibration of perovskite PV devices is very challenging due to its complex dynamic response during a conventional current-voltage (IV) measurement. PV researchers have previously proposed several steady-state performance calibration methods to reliably extract PV efficiencies, but mostly focus on small area research-type cells. In this paper, we emphasize the importance of reliable performance calibration on large-size perovskite modules. Extending the NREL Cell and Module Performance (CMP) group’s steady-state performance calibration protocol (i.e., Asymptotic PMAX Scan) for perovskite cells to modules, we justify the necessity of reporting steady-state efficiencies for perovskite cells and discuss the challenges of applying this protocol to modules. We also present our protocol for Maximum Power Point Tracking (MPPT), which is a technique often used for performance calibration of perovskite cells and modules, and show a comparison between MPPT and Asymptotic PMAX. Using MPPT we demonstrate the interplay between metastability and degradation in perovskite modules, and emphasize the necessity to develop preconditioning protocols for stabilizing these devices. Our aim is to promote development of consensus protocols for performance calibration of perovskite modules, and to advance their credible power ratings, which will be beneficial to the growth of perovskite technology in the PV market.
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