多功能材料的新机遇

IF 0.1 Q4 MULTIDISCIPLINARY SCIENCES Tomsk State University Journal Pub Date : 2023-08-24 DOI:10.31675/1607-1859-2023-25-4-143-160
Анатолий Васильевич Мананков, Валентин Михайлович Яковлев, Александр Андреевич Локтюшин, Евгений Яковлевич Горюхин, A. V. Manankov, Valentin M. Yakovlev, Aleksandr A. Loktyushin, Evgeniy Ya. Gorukhin
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引用次数: 0

摘要

尽管需求不断变化,但硅酸盐材料在材料科学中一直占有重要地位。材料的改进要求理论的发展。技术和实验矿物学积累的丰富经验并不总是与传统观念相一致,有时根本找不到解释。在试图描述玻璃和陶瓷中异常高的扩散和结晶动力学参数时,就会出现这种情况。为了寻找解决这个问题的方法,我们需要用到自然科学中最普遍的定律,即振荡和波动理论。在人工硅酸盐体系的非平衡结晶条件下,发现了旋多分解机理,并在地球和月球的火山玻璃以及岩屑中得到证实。所提出的空间封闭动态结构模型考虑了相变动力学,当偏析产物(分子簇)的形成及其之间的键具有共振性质时。因此,创造了一类具有不同寻常的物理和化学性质组合的新型多功能材料。合成偏硅酸盐在医学(外科、牙科)、家庭生产、航空航天设备、材料科学(陶瓷、聚乙烯、油毡、沥青中的改性添加剂)、耐热耐磨衬里、黄金和矿渣管道等领域掌握了大约36项新技术应用。以联邦北纬铁路工程为例,说明了玻璃陶瓷的经济效益。
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New opportunities of multifunctional materials
Silicate materials traditionally occupy an important place in materials science, despite the ever-changing demands. The improvement of materials requires the development of theory. The extensive experience accumulated by technical and experimental mineralogy does not always agree with traditional ideas and, sometimes, does not find an explanation in them at all. Such a situation arises in trying to describe the anomalously high kinetic parameters of diffusion and crystallization in glass and ceramics. The search for a solution to the problem leads to the use of the most general laws of natural science, the theory of oscillations and waves. Under the conditions of nonequilibrium crystallization in artificial silicate systems, the mechanism of spinodal decomposition is found, which is later confirmed in volcanic glasses of the Earth and Moon as well as in tektites. The proposed model of spatially closed dynamic structures takes into account the kinetics of phase transformations, when the formation of segregation products (molecular clusters) and bonds between them is of a resonant nature. As a result, a new class of multifunctional materials with an unusual combination of physical and chemical properties is created. Synthetic metasilicates masters about three dozen new technological applications in medicine (surgery, dentistry), household production, and aerospace equipment, materials science (modifying additives in ceramics, polyethylene, linoleum, asphalt), heatand wear-resistant lining, gold and slag pipelines. The economic efficiency of glass ceramics is shown on the example of the Federal Project The Northern Latitudinal Railway.
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Tomsk State University Journal
Tomsk State University Journal MULTIDISCIPLINARY SCIENCES-
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