Hisham Alnahari, Annas Al-Sharabi, A. Al-Hammadi, Abdel-Basit Al-Odayni, Adnan Alnehia
{"title":"甘氨酸介导的CuO-Fe2O3-MgO纳米复合材料的合成:结构、光学和抗菌性能","authors":"Hisham Alnahari, Annas Al-Sharabi, A. Al-Hammadi, Abdel-Basit Al-Odayni, Adnan Alnehia","doi":"10.1177/26349833231176838","DOIUrl":null,"url":null,"abstract":"Multi-phase metal oxides nanocomposites (NCs) have attracted considerable attention due to their extraordinary properties and novel applications over monometallic ones. Hence, trimetallic oxides nanoparticles (NPs) are preferred because of their immensely improved optical, catalytic, and biological properties, but few materials have been reported. Besides, glycine is an excellent structure-directing agent for NPs production with tailored physicochemical properties. Thus, in this work, a novel tri-phase CuO–Fe2O3–MgO (1:1:1) NCs was prepared via a sol-gel method in the presence of glycine as a fuel. The obtained NCs were characterized by Fourier transmission infrared, X-ray diffraction (XRD), Scanning electron micrographs, and UV-Vis. The XRD analysis emphasized the formation of NCs with monoclinic CuO, cubic MgO, hexagonal Fe2O3, and tetragonal CuFe2O4 crystals. The average crystallite size (D) was in the order of 10th of nm as computed by Scherrer method, with ternary phase seemingly affect the straightforward influence of glycine fuel concentration on the final crystallite sizes. UV-Vis analysis indicates two optical energy bandgaps which increased as glycine concentration increase. The antibacterial test against Staphylococcus aureus and Escherichia coli bacteria revealed comparable activity to that of Azithromycin standard drug, which increased with glycine concentration increase. The glycine-based tailored structural, optical, and biological properties of such trimetallic NCs making them of considerable candidate for certain applications development, possibly electronics and antibiotics; a case that encourage further investigations.","PeriodicalId":10608,"journal":{"name":"Composites and Advanced Materials","volume":"25 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2023-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"3","resultStr":"{\"title\":\"Synthesis of glycine-mediated CuO–Fe2O3–MgO nanocomposites: Structural, optical, and antibacterial properties\",\"authors\":\"Hisham Alnahari, Annas Al-Sharabi, A. Al-Hammadi, Abdel-Basit Al-Odayni, Adnan Alnehia\",\"doi\":\"10.1177/26349833231176838\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Multi-phase metal oxides nanocomposites (NCs) have attracted considerable attention due to their extraordinary properties and novel applications over monometallic ones. Hence, trimetallic oxides nanoparticles (NPs) are preferred because of their immensely improved optical, catalytic, and biological properties, but few materials have been reported. Besides, glycine is an excellent structure-directing agent for NPs production with tailored physicochemical properties. Thus, in this work, a novel tri-phase CuO–Fe2O3–MgO (1:1:1) NCs was prepared via a sol-gel method in the presence of glycine as a fuel. The obtained NCs were characterized by Fourier transmission infrared, X-ray diffraction (XRD), Scanning electron micrographs, and UV-Vis. The XRD analysis emphasized the formation of NCs with monoclinic CuO, cubic MgO, hexagonal Fe2O3, and tetragonal CuFe2O4 crystals. The average crystallite size (D) was in the order of 10th of nm as computed by Scherrer method, with ternary phase seemingly affect the straightforward influence of glycine fuel concentration on the final crystallite sizes. UV-Vis analysis indicates two optical energy bandgaps which increased as glycine concentration increase. The antibacterial test against Staphylococcus aureus and Escherichia coli bacteria revealed comparable activity to that of Azithromycin standard drug, which increased with glycine concentration increase. The glycine-based tailored structural, optical, and biological properties of such trimetallic NCs making them of considerable candidate for certain applications development, possibly electronics and antibiotics; a case that encourage further investigations.\",\"PeriodicalId\":10608,\"journal\":{\"name\":\"Composites and Advanced Materials\",\"volume\":\"25 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2023-05-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"3\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Composites and Advanced Materials\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1177/26349833231176838\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Composites and Advanced Materials","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1177/26349833231176838","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Synthesis of glycine-mediated CuO–Fe2O3–MgO nanocomposites: Structural, optical, and antibacterial properties
Multi-phase metal oxides nanocomposites (NCs) have attracted considerable attention due to their extraordinary properties and novel applications over monometallic ones. Hence, trimetallic oxides nanoparticles (NPs) are preferred because of their immensely improved optical, catalytic, and biological properties, but few materials have been reported. Besides, glycine is an excellent structure-directing agent for NPs production with tailored physicochemical properties. Thus, in this work, a novel tri-phase CuO–Fe2O3–MgO (1:1:1) NCs was prepared via a sol-gel method in the presence of glycine as a fuel. The obtained NCs were characterized by Fourier transmission infrared, X-ray diffraction (XRD), Scanning electron micrographs, and UV-Vis. The XRD analysis emphasized the formation of NCs with monoclinic CuO, cubic MgO, hexagonal Fe2O3, and tetragonal CuFe2O4 crystals. The average crystallite size (D) was in the order of 10th of nm as computed by Scherrer method, with ternary phase seemingly affect the straightforward influence of glycine fuel concentration on the final crystallite sizes. UV-Vis analysis indicates two optical energy bandgaps which increased as glycine concentration increase. The antibacterial test against Staphylococcus aureus and Escherichia coli bacteria revealed comparable activity to that of Azithromycin standard drug, which increased with glycine concentration increase. The glycine-based tailored structural, optical, and biological properties of such trimetallic NCs making them of considerable candidate for certain applications development, possibly electronics and antibiotics; a case that encourage further investigations.