甲基铵铅卤化钙钛矿MAPbI3的合成与表征及其在光电探测器器件中的应用

Mohammad Malik Abood, Aref S. Baron, Osama Abdul Azeez Dakhil
{"title":"甲基铵铅卤化钙钛矿MAPbI3的合成与表征及其在光电探测器器件中的应用","authors":"Mohammad Malik Abood, Aref S. Baron, Osama Abdul Azeez Dakhil","doi":"10.31257/2018/jkp/2021/130203","DOIUrl":null,"url":null,"abstract":"Methyl ammonium lead iodide (CH3NH3PbI3) Perovskite was synthesized by a mixing method in one and two steps. The ethanol solvent was also used to dissolve CH3NH3I that is compared with isopropanol solvent. The characterizations of synthesized perovskite samples include the structural properties, morphological characteristics, and optical properties. The intensity and orientation in X-ray diffraction patterns appear clearly in ethanol solvent. Additionally, the ethanol solvent increases the grain size of perovskite which is homogeneous of the surface morphology. It causes a decrease in the wavelength of absorbance edge in addition to an increase in the energy bandgap value. The photodetector parameters for MAPbI3 perovskites cover the PbS nanocrystal which was prepared on the FTO glass dissolved by Isopropanol and DMF where the responsivity Rλ= 0.0037 and the quantum efficiency QE=1.016% was under λ nm =650 nm and Vbias=0V. These values were decreased by using Ethanol solvent.","PeriodicalId":16215,"journal":{"name":"Journal of Kufa - Physics","volume":"48 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2021-12-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis and Characterization of Methyl Ammonium Lead Halide Perovskite MAPbI3 for Applications in Photodetector Devices\",\"authors\":\"Mohammad Malik Abood, Aref S. Baron, Osama Abdul Azeez Dakhil\",\"doi\":\"10.31257/2018/jkp/2021/130203\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Methyl ammonium lead iodide (CH3NH3PbI3) Perovskite was synthesized by a mixing method in one and two steps. The ethanol solvent was also used to dissolve CH3NH3I that is compared with isopropanol solvent. The characterizations of synthesized perovskite samples include the structural properties, morphological characteristics, and optical properties. The intensity and orientation in X-ray diffraction patterns appear clearly in ethanol solvent. Additionally, the ethanol solvent increases the grain size of perovskite which is homogeneous of the surface morphology. It causes a decrease in the wavelength of absorbance edge in addition to an increase in the energy bandgap value. The photodetector parameters for MAPbI3 perovskites cover the PbS nanocrystal which was prepared on the FTO glass dissolved by Isopropanol and DMF where the responsivity Rλ= 0.0037 and the quantum efficiency QE=1.016% was under λ nm =650 nm and Vbias=0V. These values were decreased by using Ethanol solvent.\",\"PeriodicalId\":16215,\"journal\":{\"name\":\"Journal of Kufa - Physics\",\"volume\":\"48 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2021-12-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Kufa - Physics\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.31257/2018/jkp/2021/130203\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Kufa - Physics","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.31257/2018/jkp/2021/130203","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0

摘要

采用一步法和两步混合法制备了碘化铅甲基铵钙钛矿。用乙醇溶剂溶解CH3NH3I,并与异丙醇溶剂进行比较。合成的钙钛矿样品的表征包括结构特性、形态特性和光学特性。在乙醇溶剂中,x射线衍射图的强度和取向清晰可见。此外,乙醇溶剂增加了钙钛矿的晶粒尺寸,使其表面形貌均匀。它引起吸光度边波长的减小和能带值的增大。MAPbI3钙钛矿的光电探测器参数覆盖了在异丙醇和DMF溶解的FTO玻璃上制备的PbS纳米晶体,其响应率Rλ= 0.0037,量子效率QE=1.016%, λ nm =650 nm, Vbias=0V。使用乙醇溶剂后,这些值有所降低。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Synthesis and Characterization of Methyl Ammonium Lead Halide Perovskite MAPbI3 for Applications in Photodetector Devices
Methyl ammonium lead iodide (CH3NH3PbI3) Perovskite was synthesized by a mixing method in one and two steps. The ethanol solvent was also used to dissolve CH3NH3I that is compared with isopropanol solvent. The characterizations of synthesized perovskite samples include the structural properties, morphological characteristics, and optical properties. The intensity and orientation in X-ray diffraction patterns appear clearly in ethanol solvent. Additionally, the ethanol solvent increases the grain size of perovskite which is homogeneous of the surface morphology. It causes a decrease in the wavelength of absorbance edge in addition to an increase in the energy bandgap value. The photodetector parameters for MAPbI3 perovskites cover the PbS nanocrystal which was prepared on the FTO glass dissolved by Isopropanol and DMF where the responsivity Rλ= 0.0037 and the quantum efficiency QE=1.016% was under λ nm =650 nm and Vbias=0V. These values were decreased by using Ethanol solvent.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
自引率
0.00%
发文量
0
期刊最新文献
Endovenous Laser Ablation of Venous Ulcers of the Lower Limbs: A Study of the Relationship between Applied Laser Power and Age/Gender Simple Scenario of Photons Emission from Anti Charm–Gluon Interaction using QCD Theory Study of geometrical properties of 96Mo, 98Ru and 100Pd isotones within interacting boson model Tunneling magnetoresistance calculation for double quantum dot connected in parallel shape to ferromagnetic Leads Enhanced the Physical Properties of Thin Films by Doping Zinc Oxide with Tin Prepared by the Pyrolysis Technique
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1