Ruifeng Zhang, Lei Liu, Weiye Yang, Yao Liu, Yingkai Liu
{"title":"提高Au@Bi2WO6花状材料对甲醛的敏感性。","authors":"Ruifeng Zhang, Lei Liu, Weiye Yang, Yao Liu, Yingkai Liu","doi":"10.1186/s11671-023-03923-4","DOIUrl":null,"url":null,"abstract":"<div><p>Bi<sub>2</sub>WO<sub>6</sub> flower-like materials (FMs) were prepared by a hydrothermal method, followed by an in-situ reduction method to prepare Au@Bi<sub>2</sub>WO<sub>6</sub> FMs. X-ray diffraction, scanning electron microscopy, transmission electron microscopy, high-resolution transmission electron microscopy, and X-ray photoelectron spectroscopy were employed to characterize the samples. It was discovered that the calculated O<sub>V</sub> content of Au@Bi<sub>2</sub>WO<sub>6</sub> FMs is 25.16% whereas that of Bi<sub>2</sub>WO<sub>6</sub> FMs is 20.81%, offering appropriate active sites for the absorption of gases and thus enhancing outstanding sensing property. Moreover, the detection of volatile and hazardous substances such as formaldehyde, methanol, acetone, benzene, toluene, and xylene was carried out to assess the efficacy of the Au@Bi<sub>2</sub>WO<sub>6</sub> FMs sensors. The optimal operating temperatures for the Bi<sub>2</sub>WO<sub>6</sub> FMs and Au@Bi<sub>2</sub>WO<sub>6</sub> FMs sensors were 290 and 260 °C, respectively. Compared with Au@Bi<sub>2</sub>WO<sub>6</sub> FMs sensor and Bi<sub>2</sub>WO<sub>6</sub> FMs one, the best response of the front was 250 (900)–100 (800) ppm formaldehyde whereas that of the latter was 90 (230). Therefore, Au@ Bi<sub>2</sub>WO<sub>6</sub> FMs have good response and selectivity, which are promising candidates for formaldehyde detection.</p></div>","PeriodicalId":715,"journal":{"name":"Nanoscale Research Letters","volume":"18 1","pages":""},"PeriodicalIF":4.7030,"publicationDate":"2023-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10643700/pdf/","citationCount":"0","resultStr":"{\"title\":\"Enhanced sensitivity of Au@Bi2WO6 flower-like materials to formaldehyde\",\"authors\":\"Ruifeng Zhang, Lei Liu, Weiye Yang, Yao Liu, Yingkai Liu\",\"doi\":\"10.1186/s11671-023-03923-4\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Bi<sub>2</sub>WO<sub>6</sub> flower-like materials (FMs) were prepared by a hydrothermal method, followed by an in-situ reduction method to prepare Au@Bi<sub>2</sub>WO<sub>6</sub> FMs. X-ray diffraction, scanning electron microscopy, transmission electron microscopy, high-resolution transmission electron microscopy, and X-ray photoelectron spectroscopy were employed to characterize the samples. It was discovered that the calculated O<sub>V</sub> content of Au@Bi<sub>2</sub>WO<sub>6</sub> FMs is 25.16% whereas that of Bi<sub>2</sub>WO<sub>6</sub> FMs is 20.81%, offering appropriate active sites for the absorption of gases and thus enhancing outstanding sensing property. Moreover, the detection of volatile and hazardous substances such as formaldehyde, methanol, acetone, benzene, toluene, and xylene was carried out to assess the efficacy of the Au@Bi<sub>2</sub>WO<sub>6</sub> FMs sensors. The optimal operating temperatures for the Bi<sub>2</sub>WO<sub>6</sub> FMs and Au@Bi<sub>2</sub>WO<sub>6</sub> FMs sensors were 290 and 260 °C, respectively. Compared with Au@Bi<sub>2</sub>WO<sub>6</sub> FMs sensor and Bi<sub>2</sub>WO<sub>6</sub> FMs one, the best response of the front was 250 (900)–100 (800) ppm formaldehyde whereas that of the latter was 90 (230). Therefore, Au@ Bi<sub>2</sub>WO<sub>6</sub> FMs have good response and selectivity, which are promising candidates for formaldehyde detection.</p></div>\",\"PeriodicalId\":715,\"journal\":{\"name\":\"Nanoscale Research Letters\",\"volume\":\"18 1\",\"pages\":\"\"},\"PeriodicalIF\":4.7030,\"publicationDate\":\"2023-11-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10643700/pdf/\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Nanoscale Research Letters\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1186/s11671-023-03923-4\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nanoscale Research Letters","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1186/s11671-023-03923-4","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Enhanced sensitivity of Au@Bi2WO6 flower-like materials to formaldehyde
Bi2WO6 flower-like materials (FMs) were prepared by a hydrothermal method, followed by an in-situ reduction method to prepare Au@Bi2WO6 FMs. X-ray diffraction, scanning electron microscopy, transmission electron microscopy, high-resolution transmission electron microscopy, and X-ray photoelectron spectroscopy were employed to characterize the samples. It was discovered that the calculated OV content of Au@Bi2WO6 FMs is 25.16% whereas that of Bi2WO6 FMs is 20.81%, offering appropriate active sites for the absorption of gases and thus enhancing outstanding sensing property. Moreover, the detection of volatile and hazardous substances such as formaldehyde, methanol, acetone, benzene, toluene, and xylene was carried out to assess the efficacy of the Au@Bi2WO6 FMs sensors. The optimal operating temperatures for the Bi2WO6 FMs and Au@Bi2WO6 FMs sensors were 290 and 260 °C, respectively. Compared with Au@Bi2WO6 FMs sensor and Bi2WO6 FMs one, the best response of the front was 250 (900)–100 (800) ppm formaldehyde whereas that of the latter was 90 (230). Therefore, Au@ Bi2WO6 FMs have good response and selectivity, which are promising candidates for formaldehyde detection.
期刊介绍:
Nanoscale Research Letters (NRL) provides an interdisciplinary forum for communication of scientific and technological advances in the creation and use of objects at the nanometer scale. NRL is the first nanotechnology journal from a major publisher to be published with Open Access.