密闭冲击射流反应器合成钴铁氧体纳米颗粒。

Abiev Rs, A. Ov, Izotova Sg, Gusarov Vv
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引用次数: 17

摘要

在相对低温(20℃~ 30℃)和环境压力下,对密闭撞击射流合成钴铁氧体的过程进行了实验研究。与通常在高压和高温(400°C至450°C)下进行的水热合成不同,撞击射流合成可以产生小颗粒(约为100 μ m)。8纳米(平均尺寸)在几毫秒内连续流动。由于试剂的短接触,其快速有效的混合可以避免副产物的形成,并排除晶体的生长。能够控制稳定和有效的流体动力学以及产品与副产品的快速分离,从而实现快速沉淀反应的最佳条件,实际上排除了大颗粒和聚集体的建立。
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Synthesis of cobalt ferrite nanoparticles by means of confined impinging-jets reactors.
The process of cobalt ferrite synthesis by means of confined impinging jets was studied experimentally at relative low temperatures (20°C to 30°C) and ambient pressure. Unlike hydrothermal synthesis usually performed at high pressures and temperatures (400°C to 450°C), impinging jets synthesis allows to produce small particles (approx. 8 nm mean size) within few milliseconds in a continuous flow. Due to short contact of reagents heir fast and effective mixing it was possible to avoid co-products formation and to exclude the growth of crystallines. Ability to control stable and effective hydrodynamics and the fast separation of products from co-products results in the optimal conditions for fast reaction of precipitation practically excluding building of large particles and aggregates.
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