有机硅流体:合成、性能和应用

P. Huber, W. Kaiser
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引用次数: 12

摘要

本文描述了“经典”有机硅流体的结构和衍生,给出了通过米勒-罗肖合成、聚合、直接合成、硅氢化和酯交换反应生产二甲基流体的反应。介绍了硅氧烷的性质,并讨论了硅氧烷流体和化合物的应用及其性质,特别是在水中的不溶性、粘温特性和介电特性。
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Silicone fluids: Synthesis, properties and applications
This paper describes the structure and derivation of ‘classical’ silicone fluids, giving the reactions for the production of dimethyl fluids by Miiller-Rochow synthesis, polymerisation, direct synthesis, hydrosilylation, and transesterification. The properties of siloxanes are described, and the applications of silicone fluids and compounds are discussed in relation to their properties, particularly insolubility in water, viscosity-temperature characteristics, and dielectric properties.
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