基于可再生资源互穿聚合物网络的热降解比较、WAXRD研究和SEM研究

B. Satpathy, N. Pal
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摘要

近年来,生物基聚合物因其对环境的友好性而受到人们的重视。作为传统补强合成聚合物的替代品,生物基聚合物来源于腰果酚等可再生资源,即CNSL的主要产物间取代酚类化合物。以大豆油聚氨酯为原料,通过缩合二氮化-4-氨基苯甲酸和3-氨基苯甲酸腰果酚染料,合成了多种ipn。用红外光谱(FTIR)、热重分析(TGA)、差示扫描量热法(DSC)对合成的ipn进行了表征。元素分析和WAXRD研究。通过热重分析和差热分析研究了ipn的热稳定性,并通过Freeman Anderson法给出了样品的热容和动力学参数(反应阶数和活化能)。
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Comparison of Thermal Degradation, WAXRD Studies and SEM of Renewable Resources Based Interpenetrating Polymer Networks
Recently bio-based polymers have received great importance due to their eco-friendly properties towards environment. As a substitute of conventional reinforcing synthetic polymer, bio-based polymers were from renewable resources like cardanol, i.e., the meta-substituted phenolic compound the chief product of CNSL. A number of IPNs have been synthesized by condensing di-azotised-4-amino benzoic acid and 3-amino benzoic acid cardanol dye with polyurethane of soybean oil. The IPNs produced have been characterized by FTIR, TGA, DSC (Differential scanning calorimetry). Elemental analysis and WAXRD studies. Thermal stability of IPNs has been studied by both TGA and DSC which provides heat capacity and kinetic parameters (order of reaction and activation energy) by Freeman Anderson method of the sample.
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