蔗渣化学改性低成本吸附剂去除涂料废水中的砷

M. A. Yalew
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引用次数: 0

摘要

砷是对环境毒性最大的重金属之一,由于其高毒性引起了社区健康问题。几种物理化学技术,如吸附、离子交换、石灰软化、反渗透、混凝和沉淀用于除砷,但在本研究中,采用吸附,因为它使用简单,吸附剂的可用性广泛。吸附法是去除废水中重金属的一种方法。虽然目前已有多种吸附剂方法用于去除不同类型的重金属离子进行研究,但以甘蔗渣为原料制备的铁浸渍活性炭作为去除水溶液中砷的潜在吸附剂进行了研究。在实验室中制备合成废水进行实验。通过批量实验确定了吸附砷的最佳条件。在恒定接触时间30min和大气温度条件下,测定了pH、吸附剂剂量、砷离子初始浓度等实验参数对砷离子初始浓度的影响。最佳条件为:pH为7,吸附剂剂量为1mg,初始浓度为20mg/L。吸附行为可以用Langmuir和Freundlich等温模型来描述。吸附数据在Langmuir等温线模型中拟合良好。在pH为7、吸附剂剂量为1g、初始砷浓度为20mg/L的条件下,吸附效率最高可达96.5%。关键词:化学活化,碳化,浸渍,活性炭,吸附,沉淀,过滤,除砷DOI: 10.7176/CER/12-10-03出版日期:2020年10月31日
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Removal of Arsenic from Paint Industries Wastewater by Chemically Modified Low Cost Adsorbent Derived from Sugar Cane Bagasse
Arsenic is one of the most toxic heavy metals to the environment which cause community health problem due to its high toxic nature. Several physiochemical techniques, such as adsorption, ion exchange, lime softening, reverse osmosis, coagulation and precipitation are used for arsenic removal but in this study, adsorption was used because of its simplicity to use and availability of a wide range of adsorbents. Adsorption is the process which is used for the removal of heavy metals from wastewater. Although there are Various adsorbents methods used to remove different type of heavy metal ions for study, iron impregnated activated carbon which was derived from sugarcane bagasse, was investigated as potential adsorbent for the removal of arsenic from aqueous solution. The synthetic wastewater was prepared in the laboratory to conduct the experiments. Batch experiments were conducted to obtain the optimum conditions for arsenic adsorption. Effect of experimental parameter such as pH, adsorbent dose, and initial arsenic ion concentration was determined at constant contact time of 30min and atmospheric temperature. The optimum conditions obtained were, pH 7, 1mg adsorbent dose and initial concentration of 20mg/L. Adsorption behavior could be described using the Langmuir and Freundlich isotherm models. Adsorption data was well fitted in Langmuir isotherm model. The maximum adsorption efficiency was found to be 96.5% at optimum experimental parameters of pH 7, adsorbent dose of 1g and initial arsenic concentration of 20mg/L. Keywords: Chemical activation, Carbonization, Impregnation, Activated Carbon, Adsorption, Settling, Filtration, Arsenic Removal DOI: 10.7176/CER/12-10-03 Publication date: October 31 st 2020
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