{"title":"1,1,1,3,3,3‐Hexafluoro‐2‐propanol","authors":"A. Phillips","doi":"10.1002/047084289X.RN01164","DOIUrl":null,"url":null,"abstract":"[920-66-1] C3H2F6O (MW 168.04) \n \nInChI = 1S/C3H2F6O/c4-2(5,6)1(10)3(7,8)9/h1,10H \n \nInChIKey = BYEAHWXPCBROCE-UHFFFAOYSA-N \n \n \n \n \n \n(highly polar, thermally stable, UV transparent solvent that is miscible with water and many polar organic solvents; additive for catalysis applications)1 \n \n \n \nAlternative Names: 1,1,1,3,3,3-hexafluoro-2-hydroxypropane; 1,1,1,3,3,3-hexafluoro-2-propanol; 1,1,1,3,3,3-hexafluoroisopropanol; 1,1,1,3,3,3-hexafluoroisopropyl alcohol; 2,2,2-trifluoro-1-(trifluoromethyl)ethanol; bis(trifluoromethyl)methanol; hexafluoroisopropanol; hexafluoroisopropyl alcohol; HFIP, HFIPA, HFP. \n \n \n \nPhysical Data: bp 58.2 °C/760 mmHg; mp −3.3 °C; d 1.6047 g cm−3; pKa = 9.3.2 \n \n \n \nAnalysis of Reagent Purity: generally used as supplied (>99% technical or >99.97 specialty grade). \n \n \n \nForm Supplied in: water-white liquid; commercially available. \n \n \n \nHandling, Storage, and Precautions: corrosive to eyes on contact and a strong skin and respiratory irritant. May contain traces of 1,1,1,3,3,3-hexafluoroacetone, a potential reproductive hazard. Appropriate precautions should be taken to minimize exposure. \n \n \n \nSolubility: miscible with water and most organic solvents, with the exception of long-chain hydrocarbon solvents.","PeriodicalId":11669,"journal":{"name":"Encyclopedia of Reagents for Organic Synthesis","volume":"1 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2010-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Encyclopedia of Reagents for Organic Synthesis","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1002/047084289X.RN01164","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
[920-66-1] C3H2F6O (MW 168.04)
InChI = 1S/C3H2F6O/c4-2(5,6)1(10)3(7,8)9/h1,10H
InChIKey = BYEAHWXPCBROCE-UHFFFAOYSA-N
(highly polar, thermally stable, UV transparent solvent that is miscible with water and many polar organic solvents; additive for catalysis applications)1
Alternative Names: 1,1,1,3,3,3-hexafluoro-2-hydroxypropane; 1,1,1,3,3,3-hexafluoro-2-propanol; 1,1,1,3,3,3-hexafluoroisopropanol; 1,1,1,3,3,3-hexafluoroisopropyl alcohol; 2,2,2-trifluoro-1-(trifluoromethyl)ethanol; bis(trifluoromethyl)methanol; hexafluoroisopropanol; hexafluoroisopropyl alcohol; HFIP, HFIPA, HFP.
Physical Data: bp 58.2 °C/760 mmHg; mp −3.3 °C; d 1.6047 g cm−3; pKa = 9.3.2
Analysis of Reagent Purity: generally used as supplied (>99% technical or >99.97 specialty grade).
Form Supplied in: water-white liquid; commercially available.
Handling, Storage, and Precautions: corrosive to eyes on contact and a strong skin and respiratory irritant. May contain traces of 1,1,1,3,3,3-hexafluoroacetone, a potential reproductive hazard. Appropriate precautions should be taken to minimize exposure.
Solubility: miscible with water and most organic solvents, with the exception of long-chain hydrocarbon solvents.
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