电子束3d打印制备镍铬不锈钢和h20n80合金梯度材料的特性

V. Moskvina, E. Melnikov, E. Zagibalova
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摘要

增材制造铬镍奥氏体不锈钢的主要问题是两相γ-奥氏体/δ-铁素体枝晶组织的形成,这使其使用复杂化,并使其与铸造的单相类似物区别开来。形成两相结构的原因是不平衡凝固条件、复杂的热历史和奥氏体形成元素(镍和锰)的熔体耗损。因此,在钢的增材制造中添加镍合金可以稳定钢的奥氏体组织。本文采用电子束增材生产的方法,同时喂入奥氏体不锈钢Fe-18.2Cr-9.5Ni-1.1Mn-0.7Ti-0.5Si-0.08C wt.% (SS, Cr18Ni10Ti)和合金77.7Ni-19.6Cr-1.8Si-0.5Fe-0.4Zr wt.% (Ni-Cr alloy, Cr20Ni80)两种钢丝,得到两种梯度坯。作者采用了两种送丝策略(第一种是四层SS/一层Cr20Ni80;第二种是一层SS/一层80% SS + 20% Cr20Ni80的混合物)。研究发现,在电子束添加剂生产SS方坯的过程中,Ni-Cr合金抑制了δ-铁素体的形成,有助于奥氏体相的稳定。Ni-Cr合金在四层SS旁的沉积导致坯料组织和化学成分不均匀,塑性低,在拉伸试验中过早失效。纯SS层与混合丝层(80% SS + 20% Cr20Ni80)的顺序交替促进了两种丝成分的均匀混合,并在梯度坯料中形成了更均匀的组织,从而导致力学试验中试样的延展性增加。
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CHARACTERISTICS OF A GRADIENT MATERIAL BASED ON NI-CR STAINLESS STEEL AND H20N80 ALLOY PRODUCED BY ELECTRON-BEAM 3D-PRINTING
The main problem of additively manufactured chromium-nickel austenitic stainless steels is the formation of a two-phase γ-austenite/δ-ferrite dendritic microstructure, which complicates their use and distinguishes them from cast single-phase analogs. The reasons for the formation of a two-phase structure are nonequilibrium solidification conditions, complex thermal history, and melt depletion by austenite-forming elements (nickel and manganese). Therefore, additional nickel alloying under the additive manufacturing of steels can stabilize the austenitic structure in them. In this work, the authors used electron-beam additive production with simultaneous feeding of two wires from austenitic stainless steel Fe-18.2Cr-9.5Ni-1.1Mn-0.7Ti-0.5Si-0.08C wt.% (SS, Cr18Ni10Ti) and alloy 77.7Ni-19.6Cr-1.8Si-0.5Fe-0.4Zr wt.% (Ni-Cr alloy, Cr20Ni80) to obtain two gradient billets. The authors used two wire-feeding strategies (the first one is four layers of SS/one layer of Cr20Ni80; the second one is one layer of SS/one layer of a mixture 80 % SS + 20 % Cr20Ni80). The study identified that the Ni-Cr alloying in the process of electron-beam additive production of SS billets suppressed δ-ferrite formation and contributes to the stabilization of the austenite phase. The deposition of Ni-Cr alloy next to the four layers of SS leads to inhomogeneity of the structure and chemical composition in the billet, low plasticity, and premature failure of these specimens during tensile tests. The sequential alternation of pure SS layers with those of a mixture of wires (80 % SS + 20 % Cr20Ni80) promotes the uniform mixing of two wires components and the formation of a more homogeneous structure in the gradient billet, which leads to an increase in the ductility of the specimens during mechanical tests.
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THE RESEARCH OF AGING AND MECHANICAL PROPERTIES OF NANOSTRUCTURAL TITANIUM The research of the processes of formation of porous non-ferrous metals Special aspects of strain localization during thermal power processing Regulation of powder particles shape and size at plasma spraying The enhancement of cutting capacity of a grinding wheel when processing ductile steel blank parts by ultrasonic activation
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