生物滴滤池中丙烯酸涂料稀释剂气体的微生物降解途径及不同气体浓度下的动力学模型比较

Q2 Materials Science Revista de Chimie Pub Date : 2022-01-31 DOI:10.37358/rc.22.1.8508
Qinwei Jia, Jun Zhou, Haonan Zhang, Tong-jiu Zuo, Luyu Wang, Lei Gong, Feng Geng
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引用次数: 0

摘要

本研究探讨了污染物进口浓度、空床停留时间(EBRT)和液体循环速度对BTF性能的影响。结果表明,该生物滴滤器在进口浓度为500 mg/m3, EBRT为300s,液体循环速度为25.46 m h-1时的最佳运行特性。在此条件下,对污染物的总去除率可达90%以上。其中,甲苯和乙苯的去除率在95%以上,对二甲苯(间二甲苯、邻二甲苯)的去除率可达70%以上,对应的去除率(ECs)分别为3.02 μ} 0.33 g m-3 h-1、1.81 μ} 0.2 g m-3 h-1、0.60 μ} 0.07 g m-3 h-1。通过脂肪酸鉴定系统和16S rDNA鉴定,可以发现4种优势菌(蜡样芽孢杆菌、枯草芽孢杆菌、钙酸不动杆菌、贝伦芽孢杆菌)对丙烯酸涂料稀释剂的去除效果显著。根据气相色谱法对有机化合物的检测以及四种优势菌产生的相应酶,可以推断出微生物降解污染物的途径。分别采用吸附-生物膜理论和吸附-生物膜理论对不同浓度废气的降解过程进行了模拟和验证。
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Microbial Degradation Pathways of Acrylic Paint Thinner Gas in Biotrickling Filter and Comparison of Kinetic Models Under Different Gas Concentrations
In this study, the effect of inlet concentration of pollutants, empty bed residence time (EBRT) and liquid recycling velocity on the performance of the BTF was explored. The results showed the best operating characteristics of the biotrickling filter for this study were at an inlet concentration of 500 mg/m3�Cthe EBRT of 300s and liquid recycling velocity of 25.46 m h-1. At this condition, the total removal efficiency of pollutants can reach more than 90%. Among them, the removal efficiency of toluene and ethylbenzene was above 95%, and the xylene (m-xylene, o-xylene) could reach more than 70%, corresponding to elimination capacities (ECs) of 3.02 �} 0.33 g m-3 h-1, 1.81 �} 0.2 g m-3 h-1, 0.60 �} 0.07 g m-3 h-1. Through the fatty acid identification system and 16S rDNA identification, it could be found that the four dominant bacteria (Bacillus cereus, Bacillus subtilis, Acinetobacter calcoaceticus, Belem Bacillus) had a significant effect on the removal of acrylic paint thinner. According to the detection of organic compounds by gas chromatography and the corresponding enzymes produced by four dominant bacteria, the pathways for microorganisms to degrade pollutants could be inferred. The absorption-biofilm theory and the adsorption-biofilm theory were used to simulate and verify the degradation process of exhaust gas at different concentrations respectively.
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来源期刊
Revista de Chimie
Revista de Chimie 化学-工程:化工
自引率
0.00%
发文量
54
审稿时长
3-6 weeks
期刊介绍: Revista de Chimie publishes original scientific studies submitted by romanian and foreign researchers and offers worldwide recognition of articles in many countries enabling their review in the publications of other researchers. Published articles are in various fields of research: * Chemistry * Petrochemistry * Chemical engineering * Process equipment * Biotechnology * Environment protection * Marketing & Management * Applications in medicine * Dental medicine * Pharmacy
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