石榴皮储能材料活性炭的制备及电化学性能研究

M. Morad, S. Attia, S. Mohamed, M. Moharam, R. Abou-shahba, M. Rashad
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摘要

研究了石榴皮在不同温度下经干燥、炭化、KOH活化制备的活性炭的电化学性能。表征结果表明,所制备的AC为非晶型碳,具有致密的层状堆叠层,具有相互连接的微孔网络,其表面积达到了惊人的3128.86m2g-1。合成的交流电在0.5 a g-1电流下的电容值为126 F -1,在2 a g-1电流密度下循环2000次后的存储保留率为137%。同时,进行了真实对称仿真,结果表明,当功率密度为244w kg-1时,电池的能量密度为4.58 W h kg-1,当电流密度为2a g-1时,经过2000次循环后,电池的储能容量为初始容量的66%。总的来说,这些结果表明,对于超级电容器的评估,交流电极可以被认为是一种成功的电极材料。
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PREPARATION AND ELECTROCHEMICAL BEHAVIOR OF THE ACTIVATED CARBON FROM POMEGRANATE PEELS AS ENERGY-STORAGE MATERIALS
This study investigates the electrochemical evaluation of the activated carbon (AC) prepared from pomegranate peels which were collected, dried, carbonized and finally activated with KOH at different temperatures. The characterization of the as-prepared AC revealed an amorphous type of carbon and densely layer-stacking sheets with an interconnected micro porous network with a remarkable 3128.86m2g-1 surface area. The as-synthesized AC displayed a remarkable capacitance of 126 F g-1 at 0.5 A g-1with a storage retention of 137 % after 2000 cycles at a current density of 2 A g-1.  Meanwhile, the realistic symmetrical simulation has been installed, it shows an energy density of 4.58 W h kg-1 at a power density of 244 W kg-1 with a storage retention of 66 % of the initial capacity at a current density of 2 A g-1 after 2000 cycles. Overall, these results demonstrate that for supercapacitors evaluation, the AC electrode can be considered a successful electrode material.
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