氦系统的二体等电子模型

A. Bhalekar, R. Santilli
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引用次数: 3

摘要

在之前的工作中,我们中的一个人(R. M. Santilli)已经证明,根据量子化学,相同的电子不能产生发生在分子结构中的强键,因为它们具有强烈的排斥库仑相互作用;将强子化学构建为量子化学的非统一覆盖,仅在相互距离为10-13cm时有效;在价电子波包的深度穿透中引入了接触式非哈密顿相互作用,克服了库仑斥力,形成了单线态价电子对的强吸引力键,称为“等电子”,并表明新的价电子键可以精确地、时不变地表示氢和水分子的结合能。利用这些进展和我们的推论(根据原子的孤对电子形成由G. N. Lewis确定的座标共价键的事实),孤对电子确实是等电子,在这篇论文中,我们显然是第一次提出了一个新的氦原子结构模型,命名为“等氦”。其中,给定轨道的两个电子强耦合成等电子,提供了泡利不相容原理的定量描述。特别地,由于Santilli等电子的强束缚态,使等氦化约为两体系统,从而允许精确解析解。所提出的解析解适用于所有类氦系。用它计算了类氦系原子核上的有效电荷,与文献值非常吻合。
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Two Body IsoElectronium Model of the Heliumic Systems
In preceding works, one of us (R. M. Santilli) has shown that, according to quantum chemistry, identical electrons cannot create the strong bond occurring in molecular structures due to their strongly repulsive Coulomb interaction; has constructed hadronic chemistry as a non-unitary covering of quantum chemistry solely valid at mutual distances of 10-13cm; has introduced contact non-Hamiltonian interactions in the deep penetration of the wavepackets of valence electrons that overcomes said Coulomb repulsion, resulting in a strongly attractive bond of valence electron pairs in singlet called ’isoelectronium’ and shown that the new valence bond allows an exact and time invariant representation of the binding energy of the hydrogen and water molecules. By using these advances and our inference that (from the fact that an atomic lone pair of electrons form a coordinate covalent bond identified by G. N. Lewis) the lone pairs of electrons are indeed isoelectronium, in this paper we present, apparently for the first time, a new structure model of the Helium atom under the name of Iso-Helium, in which the two electrons of a given orbital are strongly coupled into the isoelectronium that provided a quantitative description of Pauli exclusion principle. In particular, as a result of the strongly bound state of Santilli isoelectronium, the iso-Helium reduces to be a two-body system, thus admitting exact analytic solution. The presented analytic solution is applicable to all Helium-like systems. Using it we have calculated effective charge on the nuclei of Helium-like systems that are in excellent agreement with the literature values.
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