基于钛和碳的耦合纳米材料去除纳多洛尔

Andrijana Vukojević, Maria M. Savanović, Nataša Totić, S. Armaković, S. Pelemiš, Sanja J. Arma-Ković
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摘要

纳多洛尔(Nadolol, NAD)是β受体阻滞剂的代表之一,用于治疗心绞痛、高血压等心血管疾病。由于它的频繁使用,在医院废水中检测到它的去除效率不够,所以它进入了自然水域。由于缺乏一种令人满意的从废水中去除NAD的有效方法,因此需要找到一种更有效的去除方法。本文旨在研究不同碳含量(9 wt%和20 wt%)的TiO2-C纳米复合材料在紫外辐射下光催化降解NAD的效率。与直接光解相比,溶胶-凝胶水热法合成的纳米复合材料对NAD的去除效果显著。同时计算了NAD在TiO2-C存在下发生准一级分解的反应速率常数。采用HPLC-PDA技术监测NAD的降解情况。
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REMOVAL OF NADOLOL USING COUPLED NANOMATERIALS BASED ON TITANIUM AND CARBON
Nadolol (NAD), one of the representatives of β-blockers, is used to treat cardiovascular diseases such as angina and hypertension. Due to its frequent use, it has been detected in hospital wastewater from which it is not removed efficiently enough, so it reaches natural waters. The lack of a satisfactorily efficient method for removing NAD from wastewater has created a need to find a more efficient way for its removal. This paper aims to investigate the efficiency of photocatalytic degradation of NAD by two TiO2-C nanocomposites with different carbon content (9 and 20 wt%) under UV radiation. The applied nanocomposites, synthesized by the sol-gel hydrothermal method, showed significant efficiency in removing NAD compared to direct photolysis. Also, the reaction rate constant, according to which the decomposition of NAD in the presence of TiO2-C takes place in the pseudo-first order, was calculated. The degradation of NAD was monitored by HPLC–PDA technique.
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